Baizhi Li, Zaixing Jiang, Shuangfang Lu*, Nengwu Zhou*, Junjie Wang, Xinyu Jiang, Yang Liu, Wenbiao Li and Pengfei Zhang,
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引用次数: 0
Abstract
Exploration of Permian shale gas in the Hongxing area has expanded the Sichuan Basin’s potential, but transitional shale reservoir research is scarce, impeding the assessment of prospective shale gas zones. Here, we employ geochemical analysis, low-temperature CO2 and N2 adsorption, nuclear magnetic resonance, and field emission scanning electron microscopy to characterize lithofacies in the Permian shale. We identified four shale lithologies: carbon-rich siliceous shale (RS), carbon-rich mixed shale (RM), carbon-rich calcareous shale (RC), and carbon-poor calcareous shale (LC). RS and RM display superior pore volumes (14.33 cm3/g and 16.58 cm3/g, respectively) and specific surface areas (19.21 m2/g and 16.58 m2/g), highlighting their potential as the most promising lithofacies for shale gas development. Overall, the shales in the Hongxing area show poor pore connectivity, with liquid mobility rates of 37.84%, 24.33%, 18.75%, and 29.48% for RS, RM, RC, and LC, respectively. The corresponding T2cutoff values are 2.86, 1.74, 3.47, and 4.57 ms. Liquid mobility is primarily influenced by siliceous and calcareous minerals, while T2cutoff is controlled by clay minerals and pyrite. Organic matter (including its type, abundance, and maturity) predominantly affects micropore development, while mesopores are mainly influenced by siliceous minerals, clay minerals, and pyrite. Macropore development is primarily controlled by calcareous minerals. Depositional environments significantly influence lithofacies development: RS and RM were formed in reducing saline to brackish conditions, while RC and LC originated in oxidizing freshwater settings. Reducing estuarine and lagoonal settings with saline to brackish conditions represent the favorable depositional facies for shale development.
期刊介绍:
Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.