Lithology, Reservoir Characteristics, Formation Mechanism, and Significance of Permian Shale in the Hongxing Area, Sichuan Basin, China

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-03-10 DOI:10.1021/acs.energyfuels.4c06407
Baizhi Li, Zaixing Jiang, Shuangfang Lu*, Nengwu Zhou*, Junjie Wang, Xinyu Jiang, Yang Liu, Wenbiao Li and Pengfei Zhang, 
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Abstract

Exploration of Permian shale gas in the Hongxing area has expanded the Sichuan Basin’s potential, but transitional shale reservoir research is scarce, impeding the assessment of prospective shale gas zones. Here, we employ geochemical analysis, low-temperature CO2 and N2 adsorption, nuclear magnetic resonance, and field emission scanning electron microscopy to characterize lithofacies in the Permian shale. We identified four shale lithologies: carbon-rich siliceous shale (RS), carbon-rich mixed shale (RM), carbon-rich calcareous shale (RC), and carbon-poor calcareous shale (LC). RS and RM display superior pore volumes (14.33 cm3/g and 16.58 cm3/g, respectively) and specific surface areas (19.21 m2/g and 16.58 m2/g), highlighting their potential as the most promising lithofacies for shale gas development. Overall, the shales in the Hongxing area show poor pore connectivity, with liquid mobility rates of 37.84%, 24.33%, 18.75%, and 29.48% for RS, RM, RC, and LC, respectively. The corresponding T2cutoff values are 2.86, 1.74, 3.47, and 4.57 ms. Liquid mobility is primarily influenced by siliceous and calcareous minerals, while T2cutoff is controlled by clay minerals and pyrite. Organic matter (including its type, abundance, and maturity) predominantly affects micropore development, while mesopores are mainly influenced by siliceous minerals, clay minerals, and pyrite. Macropore development is primarily controlled by calcareous minerals. Depositional environments significantly influence lithofacies development: RS and RM were formed in reducing saline to brackish conditions, while RC and LC originated in oxidizing freshwater settings. Reducing estuarine and lagoonal settings with saline to brackish conditions represent the favorable depositional facies for shale development.

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四川盆地红星地区二叠系页岩岩性、储层特征、形成机制及意义
红星地区二叠系页岩气的勘探扩大了四川盆地的潜力,但过渡性页岩储层研究较少,影响了页岩气远景区评价。本文采用地球化学分析、低温CO2和N2吸附、核磁共振和场发射扫描电镜等方法对二叠系页岩进行岩相表征。我们确定了四种页岩岩性:富碳硅质页岩(RS)、富碳混合页岩(RM)、富碳钙质页岩(RC)和贫碳钙质页岩(LC)。RS岩相和RM岩相孔隙体积(分别为14.33 cm3/g和16.58 cm3/g)和比表面积(分别为19.21和16.58 m2/g)优越,是页岩气开发潜力最大的岩相。总体而言,红星地区页岩孔隙连通性较差,RS、RM、RC和LC的流体迁移率分别为37.84%、24.33%、18.75%和29.48%。相应的t2截止值分别为2.86、1.74、3.47和4.57 ms。液体的流动性主要受硅质和钙质矿物的影响,而t2截流则受粘土矿物和黄铁矿的控制。有机质(包括有机质类型、丰度和成熟度)主要影响微孔发育,而中孔发育主要受硅质矿物、粘土矿物和黄铁矿的影响。大孔发育主要受钙质矿物控制。沉积环境对岩相发育有显著影响:RS和RM形成于还原咸淡-半咸淡环境,RC和LC形成于氧化淡水环境。咸水到半咸水的河口和泻湖环境是页岩发育的有利沉积相。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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