Maren Neubrand, Jessica Stubbe, Richard Rudolf, Robert R. M. Walter, Maite Nößler, Biprajit Sarkar
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引用次数: 0
Abstract
Capturing atmospheric CO2 and converting it to valuable chemicals are important goals in contemporary science. We present here a simple, transition metal-free triazolylidene–borane adduct that can capture atmospheric CO2 and convert it to formate. Several key intermediates were isolated and characterized by a combination of multinuclear NMR spectroscopy, IR spectroscopy and single crystal X-ray diffraction. A first closed cycle for the conversion of CO2 to formic acid by using the aforementioned triazolylidene–borane compound is presented as well.
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Chemistry—A European Journal is a truly international journal with top quality contributions (2018 ISI Impact Factor: 5.16). It publishes a wide range of outstanding Reviews, Minireviews, Concepts, Full Papers, and Communications from all areas of chemistry and related fields.
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