Maren Neubrand, Jessica Stubbe, Richard Rudolf, Robert R M Walter, Maite Nößler, Biprajit Sarkar
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引用次数: 0
Abstract
Capturing atmospheric CO2 and converting it to valuable chemicals are important goals in contemporary science. Here, we present a simple, transition metal-free triazolylidene-borane adduct that can capture atmospheric CO2 and convert it to formate. Several key intermediates were isolated and characterized by a combination of multinuclear NMR spectroscopy, IR spectroscopy and single-crystal X-ray diffraction. The first closed cycle for the conversion of CO2 to formic acid by using the aforementioned triazolylidene-borane compound is also presented.
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