Linking the pyramid distortion to luminescence in Sb-based metal halide by best fitted ideal polyhedron characterization†

IF 5.1 2区 材料科学 Q2 MATERIALS SCIENCE, MULTIDISCIPLINARY Journal of Materials Chemistry C Pub Date : 2025-03-05 DOI:10.1039/D5TC00556F
Yunfeng Fang, Yuchen Zhang, Leopoldo Suescun, Mingyue Chen, Zhen Song and Quanlin Liu
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Abstract

Sb-based metal halides have been a research focus because of their excellent optical properties. Pyramid-like [SbCl5] polyhedra are the most distinct crystallographic feature. We analyzed 56 luminescent Sb-based hybrids from a list of 120 Sb chlorides by finding the corresponding best fitted ideal polyhedron. The results show a significant correlation between the distortion and photoluminescent quantum yield.

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通过最佳拟合理想多面体表征将sb基金属卤化物的金字塔畸变与发光联系起来
银基金属卤化物因其优异的光学性能而成为研究热点。金字塔状[SbCl5]多面体是最明显的晶体学特征。我们分析了120种Sb氯化物中56种发光Sb基杂化体,找到了最适合的理想多面体。结果表明,畸变与光致发光量子产率之间存在显著的相关性。
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来源期刊
Journal of Materials Chemistry C
Journal of Materials Chemistry C MATERIALS SCIENCE, MULTIDISCIPLINARY-PHYSICS, APPLIED
CiteScore
10.80
自引率
6.20%
发文量
1468
期刊介绍: The Journal of Materials Chemistry is divided into three distinct sections, A, B, and C, each catering to specific applications of the materials under study: Journal of Materials Chemistry A focuses primarily on materials intended for applications in energy and sustainability. Journal of Materials Chemistry B specializes in materials designed for applications in biology and medicine. Journal of Materials Chemistry C is dedicated to materials suitable for applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry C are listed below. This list is neither exhaustive nor exclusive. Bioelectronics Conductors Detectors Dielectrics Displays Ferroelectrics Lasers LEDs Lighting Liquid crystals Memory Metamaterials Multiferroics Photonics Photovoltaics Semiconductors Sensors Single molecule conductors Spintronics Superconductors Thermoelectrics Topological insulators Transistors
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