Thermolysis of Intumescent Fire-Protective Compositions Comprising Silane-Terminated Polymers

IF 1.5 4区 化学 Q4 CHEMISTRY, PHYSICAL Doklady Physical Chemistry Pub Date : 2025-03-21 DOI:10.1134/S001250162560007X
A. E. Sultangaleeva, V. E. Subbotin, A. Yu. Shchepetova, N. V. Yashin, V. V. Avdeev
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Abstract

The effects of components of intumescent systems based on silane-terminated polyether (STP) polymers on their thermolysis character were studied. Thermal analysis and fire-resistance tests showed that neither the molecular weight of the STP polymer, nor a moderate change in the ratio of components in the intumescent system relative to the selected base composition, has a significant effect on the thermolysis, whereas a change in the amounts of fillers such as kaolin and, in particular, titania, provides doubling of the fireproof rating of the studied coatings due to the structuring of the char foam formed upon thermal destruction and acts as a heat-insulating coating. These results may be of significant importance in the development of heat-expanding fire-protection compositions based on STP polymers.

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包含硅烷端部聚合物的膨胀防火组合物的热裂解
研究了硅烷端端聚醚(STP)聚合物膨胀体系组分对其热裂解性能的影响。热分析和耐火测试表明,无论是STP聚合物的分子量,还是膨胀体系中组分相对于所选碱组成的比例的适度变化,都不会对热裂解产生显著影响,而填充物(如高岭土,特别是二氧化钛)的量的变化,都不会对热裂解产生显著影响。由于炭泡沫在热破坏后形成的结构,使所研究的涂层的防火等级提高了一倍,并充当隔热涂层。这些结果可能对开发基于STP聚合物的热膨胀防火组合物具有重要意义。
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来源期刊
Doklady Physical Chemistry
Doklady Physical Chemistry 化学-物理化学
CiteScore
1.50
自引率
0.00%
发文量
9
审稿时长
6-12 weeks
期刊介绍: Doklady Physical Chemistry is a monthly journal containing English translations of current Russian research in physical chemistry from the Physical Chemistry sections of the Doklady Akademii Nauk (Proceedings of the Russian Academy of Sciences). The journal publishes the most significant new research in physical chemistry being done in Russia, thus ensuring its scientific priority. Doklady Physical Chemistry presents short preliminary accounts of the application of the state-of-the-art physical chemistry ideas and methods to the study of organic and inorganic compounds and macromolecules; polymeric, inorganic and composite materials as well as corresponding processes. The journal is intended for scientists in all fields of chemistry and in interdisciplinary sciences.
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