Chemical Synthesis of Strontium Molybdate in Ionic Melts of the Me,Sr||Cl,МоO4 (Ме = Li, Na, or K) Three-Component Reciprocal Systems

IF 1.5 4区 化学 Q4 CHEMISTRY, PHYSICAL Doklady Physical Chemistry Pub Date : 2025-03-21 DOI:10.1134/S0012501625600147
A. I. Rasulov, Zh. A. Kochkarov, A. K. Kabardov
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Abstract

Strontium molybdate was prepared by fluxed-melt chemical synthesis from ionic melts of the Me,Sr||Cl,МоO4 (Ме = Li, Na, or K) three-component reciprocal salt pair systems fluxed with the low-melting-point eutectic melt of the LiCl–NaCl–SrCl2 three-component system as the flux electrolyte. The eutectic chloride melts used as the fluxes provided a significant decrease in temperature and an increase in reaction rate of chemical strontium molybdate synthesis in ionic melts.

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钼酸锶在Me,Sr||Cl,МоO4 (Ме = Li, Na, or K)三组分互反体系离子熔体中的化学合成
采用助熔剂-熔体化学合成法,以 Me,Sr||Cl,МоO4(Ме = Li、Na 或 K)三组分互盐对体系的离子熔体为助熔剂,以 LiCl-NaCl-SrCl2 三组分体系的低熔点共晶熔体为助熔剂电解质,制备了钼酸锶。用作助熔剂的共晶氯化物熔体显著降低了离子熔体中化学合成钼酸锶的温度,并提高了反应速率。
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来源期刊
Doklady Physical Chemistry
Doklady Physical Chemistry 化学-物理化学
CiteScore
1.50
自引率
0.00%
发文量
9
审稿时长
6-12 weeks
期刊介绍: Doklady Physical Chemistry is a monthly journal containing English translations of current Russian research in physical chemistry from the Physical Chemistry sections of the Doklady Akademii Nauk (Proceedings of the Russian Academy of Sciences). The journal publishes the most significant new research in physical chemistry being done in Russia, thus ensuring its scientific priority. Doklady Physical Chemistry presents short preliminary accounts of the application of the state-of-the-art physical chemistry ideas and methods to the study of organic and inorganic compounds and macromolecules; polymeric, inorganic and composite materials as well as corresponding processes. The journal is intended for scientists in all fields of chemistry and in interdisciplinary sciences.
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