A. I. Wozniak, A. O. Lunin, A. F. Asachenko, M. A. Topchiy, S. A. Rzhevskiy, E. V. Bermesheva, M. V. Bermeshev
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引用次数: 0
Abstract
The modification of addition poly(5-vinyl-2-norbornene) by the hydrogermylation reaction has been studied for the first time. Modification is carried out using triethylgermane as a model germane and an (NHC)Pt complex, which previously proved to be one of the most efficient catalysts of the hydrosilylation of such objects, as a catalyst. Optimization of the modification conditions of poly(5-vinyl-2-norbornene) allows the synthesis of high molecular weight soluble polymers containing 60‒65% of modified units.
期刊介绍：
Polymer Science, Series C (Selected Topics) is a journal published in collaboration with the Russian Academy of Sciences. Series C (Selected Topics) includes experimental and theoretical papers and reviews on the selected actual topics of macromolecular science chosen by the editorial board (1 issue a year). Submission is possible by invitation only. All journal series present original papers and reviews covering all fundamental aspects of macromolecular science. Contributions should be of marked novelty and interest for a broad readership. Articles may be written in English or Russian regardless of country and nationality of authors. All manuscripts are peer reviewed
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