Enhancing mechanical and swelling resistance properties of acrylonitrile butadiene rubber by the usage of graphene oxide

IF 2.8 4区 化学 Q3 POLYMER SCIENCE Journal of Polymer Research Pub Date : 2025-03-24 DOI:10.1007/s10965-025-04340-0
C. Krishnamurthy, V. Chandran
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Abstract

Graphene oxide (GO) was synthesized using a modified Hummer’s method, and the influence of GO on the curing behavior, mechanical performance, abrasion resistance, and swelling resistance of acrylonitrile butadiene rubber (NBR) nanocomposites was extensively analyzed. The curing results indicated increased torques (minimum, maximum, and delta torque) and cure rate index, while scorch time and optimum cure time were reduced. The mechanical properties of the nanocomposites improved with higher GO content. Notably, NBR containing 6 phr of GO exhibited increases of 132% in tensile strength, 58% in tear strength, 10% in abrasion resistance, and 63% in stress at 100% elongation compared to unfilled NBR. Moreover, the nanocomposites demonstrated significant enhancements in both abrasion and swelling resistance. These findings highlight the potential of GO to effectively enhance the overall properties of NBR rubber.

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利用氧化石墨烯提高丙烯腈-丁二烯橡胶的机械性能和抗膨胀性能
采用改进的Hummer法合成了氧化石墨烯(GO),并分析了氧化石墨烯对丙烯腈-丁二烯橡胶(NBR)纳米复合材料的固化性能、力学性能、耐磨性和抗膨胀性的影响。结果表明,固化后的扭矩(最小、最大和δ扭矩)和固化率指数均有所增加,而焦化时间和最佳固化时间均有所减少。随着氧化石墨烯含量的增加,纳米复合材料的力学性能得到改善。值得注意的是,与未填充的丁腈橡胶相比,含有6phr氧化石墨烯的丁腈橡胶的抗拉强度提高了132%,撕裂强度提高了58%,耐磨性提高了10%,100%伸长率时的应力提高了63%。此外,纳米复合材料在抗磨损和抗膨胀方面都有显著的增强。这些发现突出了氧化石墨烯有效提高丁腈橡胶整体性能的潜力。
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来源期刊
Journal of Polymer Research
Journal of Polymer Research 化学-高分子科学
CiteScore
4.70
自引率
7.10%
发文量
472
审稿时长
3.6 months
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.
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