Harnessing visible light for alkenylation reactions: A promising strategy in organic synthesis

IF 4.9 2区 化学 Q2 CHEMISTRY, PHYSICAL Molecular Catalysis Pub Date : 2025-03-22 DOI:10.1016/j.mcat.2025.115028
M Manod , Archana Vijayakumar , TS Abhinav , R Bharath Krishna , Chithra Mohan
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Abstract

The development of green and streamlined methods for alkenylation reactions has long been a longstanding challenge in organic synthesis. Recently, visible light-mediated alkenylation has emerged as a potent strategy for the efficient and sustainable synthesis of diverse carbon-carbon double bonds. This approach offers a more effective and environmentally friendly alternative to traditional synthetic approaches. This review highlights the latest advancements in visible light-mediated alkenylation reactions, with a focus on novel photocatalytic systems, alkene sources, and applications in complex molecule synthesis. Mechanistic insights into the role of visible light in facilitating efficient and selective alkenylation are also provided.

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利用可见光进行烯化反应:有机合成中一种前景广阔的策略
发展绿色和流线型的烯烃化反应方法一直是有机合成领域的一个长期挑战。最近,可见光介导的烯基化已成为一种有效和可持续合成各种碳-碳双键的有效策略。这种方法比传统的合成方法更有效、更环保。本文综述了可见光介导的烯基化反应的最新进展,重点介绍了新型光催化体系、烯源及其在复杂分子合成中的应用。此外,还提供了可见光在促进高效和选择性烯基化中的作用的机制见解。
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来源期刊
Molecular Catalysis
Molecular Catalysis Chemical Engineering-Process Chemistry and Technology
CiteScore
6.90
自引率
10.90%
发文量
700
审稿时长
40 days
期刊介绍: Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are: Heterogeneous catalysis including immobilized molecular catalysts Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis Photo- and electrochemistry Theoretical aspects of catalysis analyzed by computational methods
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