Coercivity improvement for vanadium carbide (VC) doped sintered Nd−Fe−B magnets: Effectively tuning microstructure Verbesserung der Koerzitivkraft von mit Vanadiumkarbid (VC) dotierten gesinterten Nd−Fe−B−Magneten: Effektive Abstimmung des Gefüges

IF 1.1 4区材料科学 Q4 MATERIALS SCIENCE, MULTIDISCIPLINARY Materialwissenschaft und Werkstofftechnik Pub Date : 2025-03-12 DOI:10.1002/mawe.202400244

Z. Wei, L. Lele, Z. Xusheng, Y. Yang, X. Jun, M. Yanjiao, Z. Hong, L. Jitao

{"title":"Coercivity improvement for vanadium carbide (VC) doped sintered Nd−Fe−B magnets: Effectively tuning microstructure\n Verbesserung der Koerzitivkraft von mit Vanadiumkarbid (VC) dotierten gesinterten Nd−Fe−B−Magneten: Effektive Abstimmung des Gefüges","authors":"Z. Wei, L. Lele, Z. Xusheng, Y. Yang, X. Jun, M. Yanjiao, Z. Hong, L. Jitao","doi":"10.1002/mawe.202400244","DOIUrl":null,"url":null,"abstract":"<p>Vanadium carbide (VC) nano-particles were introduced into sintered Nd−Fe−B magnets for the purpose of grain refinement and coercivity enhancement. The effect of vanadium carbide (VC) addition on the microstructure and magnetic properties evolution of sintered Nd−Fe−B magnets was studied. Based on the characterization results, the additive vanadium carbide (VC) nano-particles mainly reacted with rare earth (RE)-rich phase to form ferrovanadium (FeV) phase, which rooted in the grain boundary. The ferrovanadium (FeV) phase inserted influence on the dissolution-precipitation process and acted as pinning sites and heterogeneous nucleation sites, which was favorable for the grain refinement. As a result, the coercivity of sintered magnets enhanced significantly from 13.62 kOe to 16.15 kOe without obvious decline of remanence when the vanadium carbide (VC) nano-particles additive amount increased from 0 wt.–% to 0.1 wt.–%. The above findings shed light on the microstructure manipulation to obtain high performance sintered magnets.</p>","PeriodicalId":18366,"journal":{"name":"Materialwissenschaft und Werkstofftechnik","volume":"56 3","pages":"476-483"},"PeriodicalIF":1.1000,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materialwissenschaft und Werkstofftechnik","FirstCategoryId":"88","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/mawe.202400244","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

Abstract

Vanadium carbide (VC) nano-particles were introduced into sintered Nd−Fe−B magnets for the purpose of grain refinement and coercivity enhancement. The effect of vanadium carbide (VC) addition on the microstructure and magnetic properties evolution of sintered Nd−Fe−B magnets was studied. Based on the characterization results, the additive vanadium carbide (VC) nano-particles mainly reacted with rare earth (RE)-rich phase to form ferrovanadium (FeV) phase, which rooted in the grain boundary. The ferrovanadium (FeV) phase inserted influence on the dissolution-precipitation process and acted as pinning sites and heterogeneous nucleation sites, which was favorable for the grain refinement. As a result, the coercivity of sintered magnets enhanced significantly from 13.62 kOe to 16.15 kOe without obvious decline of remanence when the vanadium carbide (VC) nano-particles additive amount increased from 0 wt.–% to 0.1 wt.–%. The above findings shed light on the microstructure manipulation to obtain high performance sintered magnets.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

碳化钒（VC）掺杂烧结Nd - Fe - B磁体的强制改进：有效调整微观结构

将碳化钒（VC）纳米颗粒引入烧结Nd−Fe−B磁体中，以细化晶粒和增强矫顽力。研究了碳化钒（VC）对烧结Nd−Fe−B磁体组织和磁性能演变的影响。表征结果表明，添加剂碳化钒（VC）纳米颗粒主要与富稀土（RE）相反应形成钒铁（FeV）相，并扎根于晶界。钒铁（FeV）相的插入影响了合金的溶解-析出过程，并作为钉钉位点和非均相形核位点，有利于晶粒细化。结果表明，当碳化钒（VC）纳米颗粒的添加量从0 wt增加时，烧结磁体的矫顽力从13.62 kOe显著提高到16.15 kOe，剩余量没有明显下降。- %至0.1 wt. - %上述研究结果为制备高性能烧结磁体的微观结构操纵提供了新的思路。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Materialwissenschaft und Werkstofftechnik 工程技术-材料科学：综合

CiteScore

2.10

自引率

9.10%

发文量

154

审稿时长

4-8 weeks

期刊介绍： Materialwissenschaft und Werkstofftechnik provides fundamental and practical information for those concerned with materials development, manufacture, and testing. Both technical and economic aspects are taken into consideration in order to facilitate choice of the material that best suits the purpose at hand. Review articles summarize new developments and offer fresh insight into the various aspects of the discipline. Recent results regarding material selection, use and testing are described in original articles, which also deal with failure treatment and investigation. Abstracts of new publications from other journals as well as lectures presented at meetings and reports about forthcoming events round off the journal.