{"title":"Fe-Catalyzed C-N/C-S Bonds Formation via Activation of Csp3-H Bond of Methylarenes: A Straightforward Tandem Oxidative Process to Access Benzazoles","authors":"Fatemeh Bigdelizadeh, Dariush Khalili, Jasem Aboonajmi","doi":"10.1002/aoc.70130","DOIUrl":null,"url":null,"abstract":"<div>\n \n <p>Fe-catalyzed tandem cross-dehydrogenative coupling of the methylarenes with <i>o</i>-phenylenediamine/2-aminothiophenol as coupling partners has been developed for the synthesis of benzimidazoles and benzothiazoles. Various 2-aryl benzimidazoles/thiazoles were synthesized with high efficiency from cost-effective raw materials using <i>tert</i>-butyl hydroperoxide (TBHP) as an environmentally benign oxidant without any co-promoter and additional oxidizing reagent.</p>\n </div>","PeriodicalId":8344,"journal":{"name":"Applied Organometallic Chemistry","volume":"39 4","pages":""},"PeriodicalIF":3.7000,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Applied Organometallic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://onlinelibrary.wiley.com/doi/10.1002/aoc.70130","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
Fe-catalyzed tandem cross-dehydrogenative coupling of the methylarenes with o-phenylenediamine/2-aminothiophenol as coupling partners has been developed for the synthesis of benzimidazoles and benzothiazoles. Various 2-aryl benzimidazoles/thiazoles were synthesized with high efficiency from cost-effective raw materials using tert-butyl hydroperoxide (TBHP) as an environmentally benign oxidant without any co-promoter and additional oxidizing reagent.
期刊介绍：
All new compounds should be satisfactorily identified and proof of their structure given according to generally accepted standards. Structural reports, such as papers exclusively dealing with synthesis and characterization, analytical techniques, or X-ray diffraction studies of metal-organic or organometallic compounds will not be considered. The editors reserve the right to refuse without peer review any manuscript that does not comply with the aims and scope of the journal. Applied Organometallic Chemistry publishes Full Papers, Reviews, Mini Reviews and Communications of scientific research in all areas of organometallic and metal-organic chemistry involving main group metals, transition metals, lanthanides and actinides. All contributions should contain an explicit application of novel compounds, for instance in materials science, nano science, catalysis, chemical vapour deposition, metal-mediated organic synthesis, polymers, bio-organometallics, metallo-therapy, metallo-diagnostics and medicine. Reviews of books covering aspects of the fields of focus are also published.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
