{"title":"Advances in the selective functionalization of B(3,6)–H of o-carboranes","authors":"Ji Wu , Ke Cao","doi":"10.1039/d4ob01778a","DOIUrl":null,"url":null,"abstract":"<div><div>This review summarizes the methodologies for the selective functionalization of the B(3,6) vertices of <em>o</em>-carboranes, including the deboration-capitation reaction, the coupling reaction of B–X (X = I, Br) bonds, reactions of 1,3-dehydro-<em>o</em>-carborane and [3-N<sub>2</sub>-<em>o</em>-C<sub>2</sub>B<sub>10</sub>H<sub>11</sub>][BF<sub>4</sub>] as well as transition-metal-catalyzed B–H activation. These works offer a versatile toolbox for synthesizing B(3,6)-substituted <em>o</em>-carborane derivatives and will promote their applications in material science, pharmaceutical chemistry, and related disciplines.</div></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"23 16","pages":"Pages 3701-3711"},"PeriodicalIF":2.7000,"publicationDate":"2024-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052025002253","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
This review summarizes the methodologies for the selective functionalization of the B(3,6) vertices of o-carboranes, including the deboration-capitation reaction, the coupling reaction of B–X (X = I, Br) bonds, reactions of 1,3-dehydro-o-carborane and [3-N2-o-C2B10H11][BF4] as well as transition-metal-catalyzed B–H activation. These works offer a versatile toolbox for synthesizing B(3,6)-substituted o-carborane derivatives and will promote their applications in material science, pharmaceutical chemistry, and related disciplines.
期刊介绍：
Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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