TfOH-catalyzed Markovnikov-selective hydrothiolation of tri- and tetrasubstituted alkenes

IF 1.5 4区化学 Q3 CHEMISTRY, ORGANIC Tetrahedron Letters Pub Date : 2025-03-28 DOI:10.1016/j.tetlet.2025.155550

Takanori Shibata, Ryo Tokutake, Mamoru Ito

引用次数: 0

Abstract

Markovnikov-selective hydrothiolation of tri- and tetrasubstituted alkenes proceeds at room temperature to give various tertiary sulfides. Aryl- and alkyl-substituted alkenes, including cyclic ones, are viable substrates. In addition to alkyl and aryl thiols, thioacetic acid is also available.

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tfoh催化三取代烯烃和四取代烯烃的马尔可夫尼科夫选择性硫代氢化反应

三取代烯烃和四取代烯烃在室温下进行马尔可夫尼科夫选择性硫代氢化反应，得到各种叔硫化物。芳基和烷基取代烯烃，包括环烃，是可行的底物。除了烷基和芳基硫醇，硫乙酸也是可用的。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Tetrahedron Letters 化学-有机化学

CiteScore

3.50

自引率

5.60%

发文量

521

审稿时长

28 days

期刊介绍： Tetrahedron Letters provides maximum dissemination of outstanding developments in organic chemistry. The journal is published weekly and covers developments in techniques, structures, methods and conclusions in experimental and theoretical organic chemistry. Rapid publication of timely and significant research results enables researchers from all over the world to transmit quickly their new contributions to large, international audiences.

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