Chemical Mapping of Supramolecular Self-Assembled Monolayers via Atomic Force Microscopy-Based Infrared with a Nanometer-Scale Lateral Resolution

IF 4.6 2区 化学 Q2 CHEMISTRY, PHYSICAL The Journal of Physical Chemistry Letters Pub Date : 2025-03-27 DOI:10.1021/acs.jpclett.5c00360
Alexandre Dazzi, Frank Palmino, Ariane Deniset-Besseau, Jérémie Mathurin, Vincent Luzet, Peter De Wolf, Qichi Hu, Chunzeng Li, Cassandra Phillips, Frédéric Chérioux
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Abstract

Atomic force microscopy-based infrared (AFM-IR) techniques have long enabled chemical imaging of surfaces with spatial resolutions down to 10 nm. In this study, we push the boundaries of AFM-IR spatial resolution to the single-nanometer scale, achieving chemical mapping of supramolecular networks at the submolecular level. This breakthrough is made possible by implementing an innovative tapping-mode AFM-IR approach. Such unprecedented resolution opens new horizons for advancements in nanoscience.

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基于原子力显微镜的纳米级横向分辨率红外超分子自组装单层化学作图
基于原子力显微镜的红外(AFM-IR)技术长期以来使空间分辨率低至10纳米的表面化学成像成为可能。在这项研究中,我们将AFM-IR空间分辨率的界限推向了单纳米尺度,实现了亚分子水平上超分子网络的化学作图。这一突破是通过实施创新的分接模式AFM-IR方法实现的。这种前所未有的分辨率为纳米科学的进步开辟了新的视野。
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来源期刊
The Journal of Physical Chemistry Letters
The Journal of Physical Chemistry Letters CHEMISTRY, PHYSICAL-NANOSCIENCE & NANOTECHNOLOGY
CiteScore
9.60
自引率
7.00%
发文量
1519
审稿时长
1.6 months
期刊介绍: The Journal of Physical Chemistry (JPC) Letters is devoted to reporting new and original experimental and theoretical basic research of interest to physical chemists, biophysical chemists, chemical physicists, physicists, material scientists, and engineers. An important criterion for acceptance is that the paper reports a significant scientific advance and/or physical insight such that rapid publication is essential. Two issues of JPC Letters are published each month.
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