A. V. Medved′ko, A. M. Zakirov, M. E. Minyaev, E. V. Tretyakov, S. Z. Vatsadze
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引用次数: 0
Abstract
Molecular and crystal structures of the following bispidine conjugates with stable TEMPO radicals and their synthetic precursors are described for the first time: 4-(2-bromacetoamido)-2,2,6,6-tetramethylpiperidine-1-oxyl (2), tert-butyl-3,7-diazabicyclo[3.3.1]nonan-3-carboxylate (4), 2-(1-oxyl-2,2,6,6-tetramethylpiperidine-4-yl)acetamide (3,7-diazabicyclo[3.3.1]nonan-3-carboxylate (6) and 2,2′-(1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonan-3,7-diyl)bis[N-(2,2,6,6-tetramethyl-1-oxyl-piperidine-4-yl)acetamide] (7). These conjugates are prepared by the alkylation of bispidines using TEMPO bromo-derivatives.
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Journal is an interdisciplinary publication covering all aspects of structural chemistry, including the theory of molecular structure and chemical bond; the use of physical methods to study the electronic and spatial structure of chemical species; structural features of liquids, solutions, surfaces, supramolecular systems, nano- and solid materials; and the crystal structure of solids.
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