Cantilever-Enhanced Photoacoustic Spectroscopy: Simultaneous Demodulation of Resonant and Nonresonant Signals for the Measurement of Dual SF6 Decomposition Components

IF 6.7 1区 化学 Q1 CHEMISTRY, ANALYTICAL Analytical Chemistry Pub Date : 2025-03-31 DOI:10.1021/acs.analchem.4c03543
Hongtu Cheng, Jie Feng, Yang Shen, Zhi Fang
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Abstract

Photoacoustic spectroscopy (PAS) gas sensing systems are generally classified into resonant and nonresonant types. However, it remains unclear whether signals at both resonant and nonresonant frequencies can be demodulated by one demodulation channel and one pass cell to achieve the simultaneous detection of two target molecules. In this study, a cantilever-enhanced photoacoustic (PA) gas detection system was utilized to measure H2S and CO2, both of which have been identified as typical fault gases in SF6 gas-insulated electrical equipment. The vibration modes of the cantilever beam at its first resonant and nonresonant frequencies were simulated and analyzed. Utilizing a laser interferometer, the vibration signals of a cantilever beam were measured. The results confirm that the resonant and nonresonant components of the vibration signal can be demodulated simultaneously. Gas detection experiments were conducted using a cantilever beam-based PAS gas sensing unit. Measurements in the ternary gas mixtures demonstrated the feasibility of simultaneously detecting H2S and CO2 by extracting components at 34 and 349 Hz. The PA signals exhibited a strong linear relationship with the gas concentrations, and the detection limits of H2S and CO2 are 2.55 and 84.69 ppm, respectively.

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悬臂增强光声光谱:用于测量双SF6分解成分的共振和非共振信号的同时解调
光声光谱(PAS)气敏系统一般分为谐振型和非谐振型。然而,是否可以通过一个解调通道和一个通胞对谐振频率和非谐振频率的信号进行解调,从而实现对两个目标分子的同时检测,目前还不清楚。在本研究中,利用悬臂增强光声(PA)气体检测系统测量H2S和CO2,这两种气体已被确定为SF6气体绝缘电气设备中的典型故障气体。对悬臂梁在第一共振频率和非共振频率下的振动模态进行了模拟和分析。利用激光干涉仪对悬臂梁的振动信号进行了测量。结果表明,振动信号的谐振分量和非谐振分量可以同时解调。气体检测实验采用基于悬臂梁的PAS气体传感装置进行。在三元气体混合物中的测量表明,通过提取34和349 Hz的组分同时检测H2S和CO2是可行的。PA信号与气体浓度呈较强的线性关系,H2S和CO2的检出限分别为2.55和84.69 ppm。
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来源期刊
Analytical Chemistry
Analytical Chemistry 化学-分析化学
CiteScore
12.10
自引率
12.20%
发文量
1949
审稿时长
1.4 months
期刊介绍: Analytical Chemistry, a peer-reviewed research journal, focuses on disseminating new and original knowledge across all branches of analytical chemistry. Fundamental articles may explore general principles of chemical measurement science and need not directly address existing or potential analytical methodology. They can be entirely theoretical or report experimental results. Contributions may cover various phases of analytical operations, including sampling, bioanalysis, electrochemistry, mass spectrometry, microscale and nanoscale systems, environmental analysis, separations, spectroscopy, chemical reactions and selectivity, instrumentation, imaging, surface analysis, and data processing. Papers discussing known analytical methods should present a significant, original application of the method, a notable improvement, or results on an important analyte.
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