Oil Recovery and Fluid Configuration in High- vs Low-Salinity Waterflooding Followed by Polymer Flooding: Pore-Scale Insights

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS Energy & Fuels Pub Date : 2025-03-25 DOI:10.1021/acs.energyfuels.4c04634
Chunyu Tong, Yongfei Yang*, Qi Zhang, Haoyun Li, Lei Zhang, Hai Sun, Junjie Zhong, Kai Zhang and Jun Yao, 
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Abstract

Increasing attention is being given to low-salinity waterflooding (LSW) due to its environmental and economic advantages. While numerous scholars have researched LSW, the comprehension of its synergistic effect with other recovery techniques, such as polymer flooding, remains incomplete especially in the pore-scale remaining oil configuration. This study conducted two sets of two-phase displacement flow experiments in carbonate samples using high-salinity brine, low-salinity brine, and polymer. The high-salinity polymer flooding (HSPF) experiment served as a control to highlight the efficiency of combining low-salinity brine with polymer. A high-resolution micro-CT machine was used to acquire images of rock samples during the displacement processes. We found that the polymer after injection of the low-salinity brine was more efficient. Low-salinity brine significantly altered the wettability (from 125.13 to 104.80°) of the rock, while there was no change in the average contact angle during polymer flooding. Polymer flooding resulted in more significant ruptures of the largest clusters. Additionally, a substantial increase in the oil–water interfacial area was observed after low-salinity polymer flooding (LSPF). The synergy of LSW with polymer flooding may greatly improve oil recovery.

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高、低矿化度水驱和聚合物驱的采收率和流体结构:孔隙尺度研究
低盐度注水(LSW)因其环境和经济优势而日益受到关注。虽然已有众多学者对低盐度注水进行了研究,但对其与聚合物淹没等其他采油技术的协同效应的理解仍不全面,尤其是在孔隙尺度剩余油配置方面。本研究使用高盐度盐水、低盐度盐水和聚合物在碳酸盐岩样本中进行了两组两相置换流动实验。高盐度聚合物淹没(HSPF)实验作为对照,以突出低盐度盐水与聚合物相结合的效率。在置换过程中,我们使用高分辨率微型计算机断层扫描(Micro-CT)机获取了岩石样本的图像。我们发现,注入低盐度盐水后聚合物的效率更高。低盐度盐水明显改变了岩石的润湿性(从 125.13° 降至 104.80°),而聚合物浸润过程中的平均接触角没有变化。聚合物淹没会导致最大的岩团发生更严重的破裂。此外,在低盐度聚合物浸润(LSPF)之后,还观察到油水界面面积大幅增加。LSW 与聚合物淹没的协同作用可大大提高石油采收率。
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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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