Frederick P. Malan , Kariska Potgieter , Reinout Meijboom
{"title":"Bis[(2-methoxyphenyl)diphenylphosphane-κP](nitrito-κ2O,O′)silver(I)","authors":"Frederick P. Malan , Kariska Potgieter , Reinout Meijboom","doi":"10.1107/S2414314625001932","DOIUrl":null,"url":null,"abstract":"<div><div>The synthesis and single-crystal structure description of a silver(I) diphenyl-2-methoxyphenylphosphine nitrite complex is described.</div></div><div><div>The molecular structure of the title Ag<sup>I</sup> complex, [Ag(NO<sub>2</sub>)(C<sub>19</sub>H<sub>17</sub>OP)<sub>2</sub>], is described, where a distorted tetrahedral coordination environment for the Ag<sup>I</sup> atom is apparent within a O<sub>2</sub>P<sub>2</sub> donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H⋯O interactions are evident.<span><figure><span><img><ol><li><span><span>Download: <span>Download high-res image (432KB)</span></span></span></li><li><span><span>Download: <span>Download full-size image</span></span></span></li></ol></span></figure></span></div></div>","PeriodicalId":94324,"journal":{"name":"IUCrData","volume":"10 3","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IUCrData","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2414314625000203","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2025/3/27 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
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Abstract
The synthesis and single-crystal structure description of a silver(I) diphenyl-2-methoxyphenylphosphine nitrite complex is described.
The molecular structure of the title AgI complex, [Ag(NO2)(C19H17OP)2], is described, where a distorted tetrahedral coordination environment for the AgI atom is apparent within a O2P2 donor set as the nitrito anion coordinates in a bidentate mode. A fairly large angle for P—Ag—P [129.126 (16)°] is noted. The O—Ag—O chelate angle is = 50.38 (6)° and the P—Ag—O angles lie in the range 99.51 (5) to 118.45 (6)°. In the crystal, C—H⋯O interactions are evident.
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