Performance and Mechanism of Tailings Biochar Composites for Synergistic Phytoremediation of Soil Heavy Metal Cd

IF 3 4区 环境科学与生态学 Q2 ENVIRONMENTAL SCIENCES Water, Air, & Soil Pollution Pub Date : 2025-04-04 DOI:10.1007/s11270-025-07895-2
Han Zhang, Xiaodong Wu, Qiao Zhang, Gang Xue, Xinhui Duan, Jinsheng Liang, Cairong Gong
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Abstract

In recent years, soil heavy metal pollution and the accumulation of tailings and food waste cannot be ignored. Currently, soil remediation agents are expensive or have poor remediation effects. In this experiment, alkali-modified tailings biochar composite (MTB) was prepared by low-temperature pyrolysis using tailings and food waste as raw materials for the remediation of soil heavy metal Cd. MTB has a large number of oxygen-containing functional groups on its surface (Si–O, Fe–O, -OH, C-O, -COOH), which is favorable for the adsorption of the heavy metal Cd. The adsorption behavior is consistent with the Langmuir model and the proposed second-order kinetic equation, and the adsorption mechanism is mainly complexation and precipitation. 650 °C pyrolysis preparation of MTB3 reduced bioavailable cadmium by 83% in 35 days, and the active Cd was transformed into inactive Cd. Potting experiments showed that ryegrass biomass significantly increased.Adding 8% MTB3 to ryegrass significantly reduced Cd accumulation, lowering available cadmium by 86.4% in 35 days compared to the control (CK). Tailings biochar improved soil properties, boosting plant germination and height by 26.94% to 106%. The study showed that tailings biochar composites have good prospects for remediation of soil heavy metal Cd pollution.

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尾矿生物炭复合材料协同修复土壤重金属Cd的性能与机理
近年来,土壤重金属污染和尾矿、厨余的积累不容忽视。目前,土壤修复剂价格昂贵或修复效果较差。本实验以尾矿和食物垃圾为原料,通过低温热解法制备碱改性尾矿生物炭复合材料(MTB),用于土壤重金属Cd的修复。MTB表面含有大量含氧官能团(Si-O、Fe-O、-OH、C-O、-COOH),有利于重金属Cd的吸附,吸附行为符合Langmuir模型和所建立的二级动力学方程。吸附机理主要为络合和沉淀。650℃热解制备的MTB3在35 d内使生物可利用镉降低83%,活性Cd转化为非活性Cd。盆栽试验表明,黑麦草生物量显著增加。在黑麦草中添加8%的MTB3显著降低了Cd积累,35 d内有效镉比对照降低了86.4%。尾矿生物炭改善了土壤性质,提高了植物发芽率和高度26.94% ~ 106%。研究表明,尾矿生物炭复合材料在修复土壤重金属镉污染方面具有良好的应用前景。图形抽象
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来源期刊
Water, Air, & Soil Pollution
Water, Air, & Soil Pollution 环境科学-环境科学
CiteScore
4.50
自引率
6.90%
发文量
448
审稿时长
2.6 months
期刊介绍: Water, Air, & Soil Pollution is an international, interdisciplinary journal on all aspects of pollution and solutions to pollution in the biosphere. This includes chemical, physical and biological processes affecting flora, fauna, water, air and soil in relation to environmental pollution. Because of its scope, the subject areas are diverse and include all aspects of pollution sources, transport, deposition, accumulation, acid precipitation, atmospheric pollution, metals, aquatic pollution including marine pollution and ground water, waste water, pesticides, soil pollution, sewage, sediment pollution, forestry pollution, effects of pollutants on humans, vegetation, fish, aquatic species, micro-organisms, and animals, environmental and molecular toxicology applied to pollution research, biosensors, global and climate change, ecological implications of pollution and pollution models. Water, Air, & Soil Pollution also publishes manuscripts on novel methods used in the study of environmental pollutants, environmental toxicology, environmental biology, novel environmental engineering related to pollution, biodiversity as influenced by pollution, novel environmental biotechnology as applied to pollution (e.g. bioremediation), environmental modelling and biorestoration of polluted environments. Articles should not be submitted that are of local interest only and do not advance international knowledge in environmental pollution and solutions to pollution. Articles that simply replicate known knowledge or techniques while researching a local pollution problem will normally be rejected without review. Submitted articles must have up-to-date references, employ the correct experimental replication and statistical analysis, where needed and contain a significant contribution to new knowledge. The publishing and editorial team sincerely appreciate your cooperation. Water, Air, & Soil Pollution publishes research papers; review articles; mini-reviews; and book reviews.
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