{"title":"Electrochemical Oxidative Dibrominative Cyclization of 1,n-Enynes with Hypervalent Iodoarene Intermediates Utilizing Recyclable Bromine Ionic Liquids","authors":"Longji Li, Xu Wang, Huaibin Jiang, Yang’en You","doi":"10.1021/acs.joc.5c00049","DOIUrl":null,"url":null,"abstract":"An electrochemical approach with iodoarene as a mediator using recyclable ionic liquids to achieve dibromonative cyclization of 1,n-enynes has been reported. With recyclable bromine sources, <i>in situ</i> generation of iodine(III) compounds through electrochemical oxidation to achieve cyclization, a variety of heterocyclic frameworks containing both vinyl and alkyl bromide groups had been obtained in high yields with good selectivity.","PeriodicalId":57,"journal":{"name":"Journal of Organic Chemistry","volume":"63 1","pages":""},"PeriodicalIF":3.6000,"publicationDate":"2025-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Organic Chemistry","FirstCategoryId":"1","ListUrlMain":"https://doi.org/10.1021/acs.joc.5c00049","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
An electrochemical approach with iodoarene as a mediator using recyclable ionic liquids to achieve dibromonative cyclization of 1,n-enynes has been reported. With recyclable bromine sources, in situ generation of iodine(III) compounds through electrochemical oxidation to achieve cyclization, a variety of heterocyclic frameworks containing both vinyl and alkyl bromide groups had been obtained in high yields with good selectivity.
期刊介绍：
Journal of Organic Chemistry welcomes original contributions of fundamental research in all branches of the theory and practice of organic chemistry. In selecting manuscripts for publication, the editors place emphasis on the quality and novelty of the work, as well as the breadth of interest to the organic chemistry community.
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