On the Escape of a Diffusing Particle from a Cavity

IF 0.8 4区 化学 Q4 CHEMISTRY, PHYSICAL Russian Journal of Physical Chemistry A Pub Date : 2025-04-05 DOI:10.1134/S0036024424703308
V. Yu. Zitserman, Yu. A. Makhnovskii
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Abstract

The problem about an exit of a Brownian particle from a cylindrical cavity through an opening on the surface of one of the cylinder ends is considered. A one-dimensional description of the process using the surface homogenization method is proposed. The solution obtained by this method allows us to find the average lifetime of a particle in such a cavity with any hole size. The qualitative difference from the well-known solution for the average lifetime of a particle diffusing in an isometric (sphere-like) cavity lies in the fact that the previously obtained result depends only on the cavity volume, while the solution found in this work depends not only on the cylinder volume, but also on its length.

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论扩散粒子从空腔中的逃逸
考虑了一个布朗粒子通过圆柱体一端表面上的开口从圆柱体腔中出口的问题。提出了一种用表面均匀化方法对该过程进行一维描述的方法。用这种方法得到的解使我们能够求出在这种空腔中任意尺寸的粒子的平均寿命。与众所周知的粒子在等距(球形)腔中扩散的平均寿命的解在性质上的区别在于,先前得到的结果只取决于腔的体积,而在这项工作中发现的解不仅取决于圆柱体的体积,而且取决于其长度。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
376
审稿时长
5.1 months
期刊介绍: Russian Journal of Physical Chemistry A. Focus on Chemistry (Zhurnal Fizicheskoi Khimii), founded in 1930, offers a comprehensive review of theoretical and experimental research from the Russian Academy of Sciences, leading research and academic centers from Russia and from all over the world. Articles are devoted to chemical thermodynamics and thermochemistry, biophysical chemistry, photochemistry and magnetochemistry, materials structure, quantum chemistry, physical chemistry of nanomaterials and solutions, surface phenomena and adsorption, and methods and techniques of physicochemical studies.
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