Separation of Actinides and REEs Using TODGA in meta-Nitrobenzotrifluoride: Development and Demonstration of the Flowsheet

IF 1 Q4 CHEMISTRY, INORGANIC & NUCLEAR Radiochemistry Pub Date : 2025-04-05 DOI:10.1134/S1066362225010060
L. I. Tkachenko, E. V. Kenf, V. A. Babain, M. Yu. Alyapyshev
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Abstract

A process was developed for the extraction and separation of actinides and REEs from PUREX process raffinates using TODGA in meta-nitrobenzotrifluoride (F-3). The flowsheet proposed was tested under dynamic conditions using simulated raffinates of the PUREX process. The process includes joint extraction of actinides and REEs, nitric acid scrubbing, actinide stripping, and REE stripping. The conditions of selective stripping of minor actinides with a DTPA solution in the presence of a salting-out agent were determined.

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TODGA法分离间硝基苯并三氟中锕系元素和稀土元素:流程的开发与论证
建立了用TODGA在间硝基苯并三氟(F-3)中萃取分离PUREX工艺萃余物中的锕系元素和稀土元素的工艺。利用PUREX工艺的模拟萃余液在动态条件下对所提出的流程进行了测试。该工艺包括锕系元素和稀土元素的联合萃取、硝酸洗涤、锕系元素汽提和稀土汽提。研究了在盐析剂存在下,用DTPA溶液选择性溶出少量锕系元素的条件。
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来源期刊
Radiochemistry
Radiochemistry CHEMISTRY, INORGANIC & NUCLEAR-
CiteScore
1.30
自引率
33.30%
发文量
51
期刊介绍: Radiochemistry  is a journal that covers the theoretical and applied aspects of radiochemistry, including basic nuclear physical properties of radionuclides; chemistry of radioactive elements and their compounds; the occurrence and behavior of natural and artificial radionuclides in the environment; nuclear fuel cycle; radiochemical analysis methods and devices; production and isolation of radionuclides, synthesis of labeled compounds, new applications of radioactive tracers; radiochemical aspects of nuclear medicine; radiation chemistry and after-effects of nuclear transformations.
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