Visible-light-induced C–S bond formation of pyrazolin-5-ones with thioureas to pyrazol-4-yl carbamimidothioates

IF 4.9 2区 化学 Q2 CHEMISTRY, PHYSICAL Molecular Catalysis Pub Date : 2025-04-07 DOI:10.1016/j.mcat.2025.115086
Renhua Zheng , Haichang Guo , Xiurong Hu , Lei Wang
{"title":"Visible-light-induced C–S bond formation of pyrazolin-5-ones with thioureas to pyrazol-4-yl carbamimidothioates","authors":"Renhua Zheng ,&nbsp;Haichang Guo ,&nbsp;Xiurong Hu ,&nbsp;Lei Wang","doi":"10.1016/j.mcat.2025.115086","DOIUrl":null,"url":null,"abstract":"<div><div>A simple, highly efficient and environmentally benign method for the synthesis of pyrazol-4-yl carbamimidothioates was reported. Under visible light irradiation and Eosin Y as photocatalyst, a variety of pyrazol-4-yl carbamimidothioates were obtained in good to excellent yields via C–S bond formation of pyrazolin-5-ones with thioureas in ethanol. The protocol features the advantages of easy performance, environmental friendliness, high yields, and good functional tolerance, showing potential value for the preparation of some biologically active compounds.</div></div>","PeriodicalId":393,"journal":{"name":"Molecular Catalysis","volume":"580 ","pages":"Article 115086"},"PeriodicalIF":4.9000,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Molecular Catalysis","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S246882312500272X","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

A simple, highly efficient and environmentally benign method for the synthesis of pyrazol-4-yl carbamimidothioates was reported. Under visible light irradiation and Eosin Y as photocatalyst, a variety of pyrazol-4-yl carbamimidothioates were obtained in good to excellent yields via C–S bond formation of pyrazolin-5-ones with thioureas in ethanol. The protocol features the advantages of easy performance, environmental friendliness, high yields, and good functional tolerance, showing potential value for the preparation of some biologically active compounds.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
可见光诱导吡唑啉-5-酮与硫脲形成 C-S 键,生成吡唑-4-基硫代氨基甲酰亚胺酸盐
本研究报道了一种简单、高效且对环境无害的合成吡唑-4-基硫代氨基甲酰亚胺的方法。在可见光照射下,以 Eosin Y 为光催化剂,通过吡唑啉-5-酮与硫脲类化合物在乙醇中形成 C-S 键,获得了多种吡唑-4-基硫代氨基甲酰亚胺,收率从良好到极佳。该方法具有操作简便、环境友好、产率高、功能耐受性好等优点,对制备一些具有生物活性的化合物具有潜在价值。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Molecular Catalysis
Molecular Catalysis Chemical Engineering-Process Chemistry and Technology
CiteScore
6.90
自引率
10.90%
发文量
700
审稿时长
40 days
期刊介绍: Molecular Catalysis publishes full papers that are original, rigorous, and scholarly contributions examining the molecular and atomic aspects of catalytic activation and reaction mechanisms. The fields covered are: Heterogeneous catalysis including immobilized molecular catalysts Homogeneous catalysis including organocatalysis, organometallic catalysis and biocatalysis Photo- and electrochemistry Theoretical aspects of catalysis analyzed by computational methods
期刊最新文献
Biochemical characterization, crystal structure, and catalytic mechanism of a PET-hydrolase double mutant Chemoenzymatic synthesis of mirabegron using an engineered styrene monooxygenase Hydrogen Rich Syngas Production from Methane using Partial Oxidation over Sm-promoted Tungsten-zirconia Supported Ni Catalysts Graphical abstract TOC
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1