Sub-micrometer-thick hydrophobic zeolite corrosion-resistant coatings synthesized using solvothermal secondary growth†

IF 2.6 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY CrystEngComm Pub Date : 2025-03-18 DOI:10.1039/D5CE00118H
Ruilan Xu, Yongxuan Wang, Junhui Cai, Rui Wang, Ye Liu, Jingjing Kou, Rongrong Zhang, Xintu Lin and Yong Peng
{"title":"Sub-micrometer-thick hydrophobic zeolite corrosion-resistant coatings synthesized using solvothermal secondary growth†","authors":"Ruilan Xu, Yongxuan Wang, Junhui Cai, Rui Wang, Ye Liu, Jingjing Kou, Rongrong Zhang, Xintu Lin and Yong Peng","doi":"10.1039/D5CE00118H","DOIUrl":null,"url":null,"abstract":"<p >Solvothermal secondary growth was used to fabricate zeolite MFI anti-corrosion coatings on a stainless steel plate. Four different diols, <em>i.e.</em>, ethylene glycol, diethylene glycol, triethylene glycol, and tetraethylene glycol, were each investigated as a synthesis solvent. High-quality <em>b</em>-oriented MFI films each with a thickness of 400–500 nm were obtained. The evolution processes and the corresponding characteristics of the zeolite films were compared. FT-IR and XPS analysis of the zeolite surface functional groups demonstrated that the film hydrophobicity mainly originated from the reaction between the diol solvent and the hydrolyzed silica source. The uniform structure and the surface hydrophobicity of the resulting MFI coatings were found to offer good corrosion protection for stainless steel materials.</p>","PeriodicalId":70,"journal":{"name":"CrystEngComm","volume":" 15","pages":" 2094-2099"},"PeriodicalIF":2.6000,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"CrystEngComm","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/ce/d5ce00118h","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Solvothermal secondary growth was used to fabricate zeolite MFI anti-corrosion coatings on a stainless steel plate. Four different diols, i.e., ethylene glycol, diethylene glycol, triethylene glycol, and tetraethylene glycol, were each investigated as a synthesis solvent. High-quality b-oriented MFI films each with a thickness of 400–500 nm were obtained. The evolution processes and the corresponding characteristics of the zeolite films were compared. FT-IR and XPS analysis of the zeolite surface functional groups demonstrated that the film hydrophobicity mainly originated from the reaction between the diol solvent and the hydrolyzed silica source. The uniform structure and the surface hydrophobicity of the resulting MFI coatings were found to offer good corrosion protection for stainless steel materials.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
采用溶剂热二次生长法合成亚微米厚疏水沸石耐腐蚀涂层
采用溶剂热二次生长法在不锈钢板上制备了沸石MFI防腐涂层。四种不同的二醇,即乙二醇,二乙二醇,三乙二醇和四乙二醇,分别作为合成溶剂进行了研究。获得了高质量的b取向MFI薄膜,厚度为400-500 nm。比较了沸石膜的演化过程和相应的特性。对沸石表面官能团的FT-IR和XPS分析表明,膜的疏水性主要来源于二醇溶剂与水解二氧化硅源之间的反应。MFI涂层具有均匀的结构和表面疏水性,对不锈钢材料具有良好的防腐性能。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CrystEngComm
CrystEngComm 化学-化学综合
CiteScore
5.50
自引率
9.70%
发文量
747
审稿时长
1.7 months
期刊介绍: Design and understanding of solid-state and crystalline materials
期刊最新文献
Non-monotonic metastable zone-width behavior in cooling cocrystallization: a case study on the sulfamethazine-acetylsalicylic acid cocrystal system A preformed 1-D {Cu II2}n helical chain as precursor to a decanuclear 0-D {Cu II8Mn II2} cluster: synthesis, structure and magnetism Study on terahertz spectroscopy and weak intermolecular interactions of methylparaben under temperature effects Regulation of calcium phosphate phase transition kinetics in aqueous solution via additives The anti-crystal engineering principles of imidazolium cations for ionic liquids
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1