Green synthesis of graphene aerogel and its application in oil adsorption and phase change material

IF 3.2 4区 材料科学 Q2 CHEMISTRY, APPLIED Journal of Porous Materials Pub Date : 2024-11-19 DOI:10.1007/s10934-024-01706-5
Qi-Xian Zhang, Jian-Xin Tu, Feng-Hua Li, Xiao-Yu Zhou, Yu-Yan Sun
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Abstract

With the development of Chinese economic, watershed pollution situation is getting worse and gradually attracts people’s attention. Graphene aerogel (GA) is an ideal material for removing water pollution, due to its high porosity, high specific surface area, and stability. A green and convenient method for GA synthesis was proposed by using graphene oxide dispersion as raw material, triethanolamine as reducing agent, and Blue Moon hand sanitizer as surfactant. The microstructure, hydrophobic and mechanical properties of GA were thoroughly characterized. The adsorption of the prepared aerogel for dichloromethane and ethyl acetate was 240 and 174 times of its own mass, respectively. Moreover, it shows good recirculation adsorption capacity under the 100 compression-adsorption cycles of 50% maximum stress. A paraffin-GA phase change material with good thermal conductivity was also prepared and characterized. This indicates that the prepared GA has a wide range of applications.

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石墨烯气凝胶的绿色合成及其在石油吸附和相变材料中的应用
随着中国经济的发展,流域污染情况日益严重,逐渐引起人们的关注。石墨烯气凝胶(GA)具有孔隙率高、比表面积大、稳定性好等特点,是去除水污染的理想材料。本研究以氧化石墨烯分散体为原料,三乙醇胺为还原剂,蓝月亮洗手液为表面活性剂,提出了一种绿色、便捷的石墨烯气凝胶合成方法。对 GA 的微观结构、疏水性和机械性能进行了全面表征。制备的气凝胶对二氯甲烷和乙酸乙酯的吸附量分别是其自身质量的 240 倍和 174 倍。此外,在最大应力为 50%的 100 次压缩-吸附循环中,气凝胶显示出良好的再循环吸附能力。此外,还制备并表征了一种导热性能良好的石蜡-GA 相变材料。这表明所制备的 GA 具有广泛的应用前景。
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来源期刊
Journal of Porous Materials
Journal of Porous Materials 工程技术-材料科学:综合
CiteScore
4.80
自引率
7.70%
发文量
203
审稿时长
2.6 months
期刊介绍: The Journal of Porous Materials is an interdisciplinary and international periodical devoted to all types of porous materials. Its aim is the rapid publication of high quality, peer-reviewed papers focused on the synthesis, processing, characterization and property evaluation of all porous materials. The objective is to establish a unique journal that will serve as a principal means of communication for the growing interdisciplinary field of porous materials. Porous materials include microporous materials with 50 nm pores. Examples of microporous materials are natural and synthetic molecular sieves, cationic and anionic clays, pillared clays, tobermorites, pillared Zr and Ti phosphates, spherosilicates, carbons, porous polymers, xerogels, etc. Mesoporous materials include synthetic molecular sieves, xerogels, aerogels, glasses, glass ceramics, porous polymers, etc.; while macroporous materials include ceramics, glass ceramics, porous polymers, aerogels, cement, etc. The porous materials can be crystalline, semicrystalline or noncrystalline, or combinations thereof. They can also be either organic, inorganic, or their composites. The overall objective of the journal is the establishment of one main forum covering the basic and applied aspects of all porous materials.
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