Pressure-induced water production using a copper–chromium Prussian blue analog†

IF 9.5 2区 材料科学 Q1 CHEMISTRY, PHYSICAL Journal of Materials Chemistry A Pub Date : 2025-04-08 DOI:10.1039/D4TA08305A
Shintaro Akagi, Mayuko Tanaka, Junhao Wang, Hisao Kiuchi, Yoshihisa Harada, Yizhou Chen, Kazuhiro Marumoto, Kenta Imoto, Shin-ichi Ohkoshi and Hiroko Tokoro
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Abstract

To address the deterioration of water resources, on-site water production technologies have garnered attention. Herein, we demonstrate the example of pressure-induced water production using a copper–chromium Prussian blue analog (CuCr PBA). Applying pressure caused water droplets to generate from the CuCr PBA. Collecting the water droplets with a pipette revealed that approximately 240 g of water was obtained per 1 kg of CuCr PBA. One possible mechanism of water production could be the hydrophobization of pores at defect sites based on partial electron transfer from the oxygen of ligand water to copper upon pressure application. This article presents a new approach to water production, which is an important step towards the further development of the water environmental improvement technology.

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使用铜铬普鲁士蓝类似物进行压力诱导产水
为解决水资源环境恶化的问题,现场制水技术备受关注。在此,我们展示了使用铜铬普鲁士蓝类似物(CuCr PBA)进行压力诱导制水的实例。施加压力会使铜铬普鲁士蓝产生水滴。用移液管收集水滴后发现,每 1 千克 CuCr PBA 大约能产生 240 克水。产生水的一种可能机制是,在施加压力时,配体水的氧部分电子转移到铜上,从而使缺陷位点的孔隙疏水。本文提出了一种新的制水方法,为进一步发展水环境改善技术迈出了重要一步。
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来源期刊
Journal of Materials Chemistry A
Journal of Materials Chemistry A CHEMISTRY, PHYSICAL-ENERGY & FUELS
CiteScore
19.50
自引率
5.00%
发文量
1892
审稿时长
1.5 months
期刊介绍: The Journal of Materials Chemistry A, B & C covers a wide range of high-quality studies in the field of materials chemistry, with each section focusing on specific applications of the materials studied. Journal of Materials Chemistry A emphasizes applications in energy and sustainability, including topics such as artificial photosynthesis, batteries, and fuel cells. Journal of Materials Chemistry B focuses on applications in biology and medicine, while Journal of Materials Chemistry C covers applications in optical, magnetic, and electronic devices. Example topic areas within the scope of Journal of Materials Chemistry A include catalysis, green/sustainable materials, sensors, and water treatment, among others.
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