Utilization of sustainable nanocatalysts for the conversion of vulnerable waste oil into biodiesel

IF 4.7 2区 化学 Q2 CHEMISTRY, PHYSICAL Journal of Molecular Structure Pub Date : 2025-04-09 DOI:10.1016/j.molstruc.2025.142166
Abbas Sabahi Namini , Sunghoon Jung , Nazmiye Gökçe Altınçekiç , Hyunho Noh , Mohammad A. Khalilzadeh , Zhengchun Liu , Rajender S. Varma , Ho Won Jang , Dokyoon Kim , Mohammadreza Shokouhimehr
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Abstract

With the increasing use of fossil fuels, there is a strong demand to shift energy reliance toward biodiesel as a sustainable and alternative energy resource. The viability of producing biofuels by converting different raw materials, including rapeseed oil, palm oil, sunflower oil, soybean oil, leftover cooking oil, waste frying oil, dairy scum, chicken fat, and others, has been the subject of a focused inquiry. Catalytic transesterifications have been popular methods for producing biodiesel due to their simplicity in operation, cost-effectiveness in commercial exploitation, higher biodiesel productivity, and conversion efficiency. In industrial chemical processes, heterogeneous catalysts are widely exploited because they are easy to separate from the final product and generally maintain their catalytic activity after being recycled repeatedly. Highly advanced heterogeneous catalysts, known as nanocatalysts, are frequently deployed to accelerate biodiesel production because of their remarkable catalytic activity. This review article examines the transesterification reactions facilitated by various nanocatalysts to explore their potential for promoting sustainable processes. Selected nanocatalysts are highlighted due to their exceptional catalytic efficiency and capacity to be reused. The conclusive summary discusses the numerous existing impediments in the production of biodiesel and proposes potential future research avenues in the utilization of advanced nanocatalysts.

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利用可持续纳米催化剂将易损废油转化为生物柴油
随着化石燃料使用的增加,人们强烈要求将能源依赖转向生物柴油作为一种可持续的替代能源。通过转化不同的原料,包括菜籽油、棕榈油、葵花籽油、大豆油、剩余的烹饪油、废弃的煎炸油、乳制品渣渣、鸡脂肪等,来生产生物燃料的可行性一直是一个重点调查的主题。催化酯交换法具有操作简单、商业开发成本低、生物柴油产率高、转化效率高等优点,是制备生物柴油的常用方法。在工业化学过程中,多相催化剂因其易于从最终产物中分离,且通常在反复循环后仍能保持催化活性而被广泛利用。高度先进的非均相催化剂,即纳米催化剂,由于其显著的催化活性,经常被用于加速生物柴油的生产。本文综述了各种纳米催化剂促进的酯交换反应,以探索其促进可持续过程的潜力。选定的纳米催化剂因其卓越的催化效率和可重复使用的能力而受到重视。结论性总结讨论了生物柴油生产中存在的许多障碍,并提出了利用先进纳米催化剂的潜在未来研究途径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Journal of Molecular Structure
Journal of Molecular Structure 化学-物理化学
CiteScore
7.10
自引率
15.80%
发文量
2384
审稿时长
45 days
期刊介绍: The Journal of Molecular Structure is dedicated to the publication of full-length articles and review papers, providing important new structural information on all types of chemical species including: • Stable and unstable molecules in all types of environments (vapour, molecular beam, liquid, solution, liquid crystal, solid state, matrix-isolated, surface-absorbed etc.) • Chemical intermediates • Molecules in excited states • Biological molecules • Polymers. The methods used may include any combination of spectroscopic and non-spectroscopic techniques, for example: • Infrared spectroscopy (mid, far, near) • Raman spectroscopy and non-linear Raman methods (CARS, etc.) • Electronic absorption spectroscopy • Optical rotatory dispersion and circular dichroism • Fluorescence and phosphorescence techniques • Electron spectroscopies (PES, XPS), EXAFS, etc. • Microwave spectroscopy • Electron diffraction • NMR and ESR spectroscopies • Mössbauer spectroscopy • X-ray crystallography • Charge Density Analyses • Computational Studies (supplementing experimental methods) We encourage publications combining theoretical and experimental approaches. The structural insights gained by the studies should be correlated with the properties, activity and/ or reactivity of the molecule under investigation and the relevance of this molecule and its implications should be discussed.
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