Preparation and properties of patterned P-MWCNTs/PVDF functional membranes

IF 2.8 4区 化学 Q3 POLYMER SCIENCE Journal of Polymer Research Pub Date : 2025-04-08 DOI:10.1007/s10965-025-04364-6
Sen Yang, Ping Fang, XiLong Li, QianQian Li, YuXiang Zhou, EnRan Fan
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Abstract

This study focuses on enhancing the performance of polyvinylidene fluoride (PVDF) membranes through a straightforward and cost-effective modification process. Multi-walled carbon nanotubes (MWCNTs) and adsorbed polyacrylic acid (PAA) were introduced onto the membrane surfaces, resulting in modified substances (P-MWCNTs) that improved compatibility with solvents. Subsequently, the PVDF membrane surfaces were patterned using an embosser to evaluate the effects of this modification. The results revealed that the modified membranes in group C5 (15% PVDF, 0.40% MWCNTs, 3% PAA, 25 μm imprinting depth) achieved optimal performance, exhibiting a flux of 915.47 L/(m2·h), a retention rate of 93.37%, and a reduced contact angle of 47.9°. This patterned surface modification significantly enhanced retention performance, flux, and fouling resistance of the PVDF membranes, contributing to improved treatment efficacy and longevity, thus presenting promising application prospects.

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P-MWCNTs/PVDF图像化功能膜的制备及性能研究
本研究的重点是通过一种简单而经济的改性工艺来提高聚偏氟乙烯(PVDF)膜的性能。多壁碳纳米管(MWCNTs)和吸附的聚丙烯酸(PAA)被引入到膜表面,从而得到改善了与溶剂相容性的修饰物质(P-MWCNTs)。随后,使用压花机对PVDF膜表面进行图案化,以评估这种改性的效果。结果表明,C5组(PVDF为15%,MWCNTs为0.40%,PAA为3%,印迹深度为25 μm)改性膜的性能最佳,其通量为915.47 L/(m2·h),保留率为93.37%,接触角减小47.9°。这种图案化的表面改性显著提高了PVDF膜的滞留性能、通量和抗污性能,提高了处理效果和使用寿命,具有广阔的应用前景。
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来源期刊
Journal of Polymer Research
Journal of Polymer Research 化学-高分子科学
CiteScore
4.70
自引率
7.10%
发文量
472
审稿时长
3.6 months
期刊介绍: Journal of Polymer Research provides a forum for the prompt publication of articles concerning the fundamental and applied research of polymers. Its great feature lies in the diversity of content which it encompasses, drawing together results from all aspects of polymer science and technology. As polymer research is rapidly growing around the globe, the aim of this journal is to establish itself as a significant information tool not only for the international polymer researchers in academia but also for those working in industry. The scope of the journal covers a wide range of the highly interdisciplinary field of polymer science and technology, including: polymer synthesis; polymer reactions; polymerization kinetics; polymer physics; morphology; structure-property relationships; polymer analysis and characterization; physical and mechanical properties; electrical and optical properties; polymer processing and rheology; application of polymers; supramolecular science of polymers; polymer composites.
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