Cover Feature: Single-Atom Based Metal-Organic Frameworks for Efficient C−S Cross-Coupling (Chem. Asian J. 7/2025)

IF 3.3 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Chemistry - An Asian Journal Pub Date : 2025-04-09 DOI:10.1002/asia.202580702
Gobbilla Sai Kumar, Deepak Kumar, Aditya Thakur, Mukul Gupta, Praveen Kumar Velpula, Rabindranath Lo, Kolleboyina Jayaramulu
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Abstract

Jayaramulu Kolleboyina and co-workers engineered a nickel single-atom catalyst (UiO-66/Ni) with Ni atoms covalently anchored to defect-engineered Zr-oxide clusters in the UiO-66 framework, synthesized via a simple solution impregnation method. This catalyst shows uniform Ni atom distribution, exceptional stability, and high catalytic performance in C–S coupling reactions of aryl thiols and aryl halides, achieving high activity and selectivity across various substituents at room temperature, maintaining stability. More details can be found in article number e202401578.

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封面特征:高效C−S交叉耦合的单原子金属-有机框架(化学)。亚洲J. 7/2025)
Jayaramulu Kolleboyina及其同事设计了一种镍单原子催化剂(UiO-66/Ni),通过简单的溶液浸渍法合成,镍原子共价锚定在UiO-66框架中的缺陷工程zr -氧化物簇上。该催化剂镍原子分布均匀,稳定性好,在芳基硫醇和芳基卤化物的C-S偶联反应中具有较高的催化性能,在室温下对各种取代基具有较高的活性和选择性,保持了稳定性。详情请见编号为e202401578的文章。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
Chemistry - An Asian Journal
Chemistry - An Asian Journal 化学-化学综合
CiteScore
7.00
自引率
2.40%
发文量
535
审稿时长
1.3 months
期刊介绍: Chemistry—An Asian Journal is an international high-impact journal for chemistry in its broadest sense. The journal covers all aspects of chemistry from biochemistry through organic and inorganic chemistry to physical chemistry, including interdisciplinary topics. Chemistry—An Asian Journal publishes Full Papers, Communications, and Focus Reviews. A professional editorial team headed by Dr. Theresa Kueckmann and an Editorial Board (headed by Professor Susumu Kitagawa) ensure the highest quality of the peer-review process, the contents and the production of the journal. Chemistry—An Asian Journal is published on behalf of the Asian Chemical Editorial Society (ACES), an association of numerous Asian chemical societies, and supported by the Gesellschaft Deutscher Chemiker (GDCh, German Chemical Society), ChemPubSoc Europe, and the Federation of Asian Chemical Societies (FACS).
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