Strategies for Enhancing Stability in Electrochemical CO2 Reduction

Abstract

The electrochemical CO₂ reduction reaction (CO₂RR) holds significant promise as a sustainable approach to address global energy challenges and reduce carbon emissions. However, achieving long-term stability in terms of catalytic performance remains a critical hurdle for large-scale commercial deployment. This mini-review provides a comprehensive exploration of the key factors influencing CO₂RR stability, encompassing catalyst design, electrode architecture, electrolyzer optimization, and operational conditions. We examine how catalyst degradation occurs through mechanisms such as valence changes, elemental dissolution, structural reconfiguration, and active site poisoning and propose targeted strategies for improvement, including doping, alloying, and substrate engineering. Additionally, advancements in electrode design, such as structural modifications and membrane enhancements, are highlighted for their role in improving stability. Operational parameters such as temperature, pressure, and electrolyte composition also play crucial roles in extending the lifespan of the reaction. By addressing these diverse factors, this review aims to offer a deeper understanding of the determinants of long-term stability in the CO₂RR, laying the groundwork for the development of robust, scalable technologies for efficient carbon dioxide conversion.