{"title":"Kinetic resolution of binols and biphenols via dehydrogenative coupling with hydrosilanes catalyzed by chiral FLPs†","authors":"Zijia Zhang , Xiangqing Feng , Haifeng Du","doi":"10.1039/d5ob00347d","DOIUrl":null,"url":null,"abstract":"<div><div>A kinetic resolution of binols and biphenols has been realized <em>via</em> dehydrogenative coupling with hydrosilanes catalyzed by a frustrated Lewis pair of chiral borane and chiral phosphine. A variety of axially chiral siloxanes, along with the corresponding optically active binols and biphenols, were obtained in good yields with moderate to high enantioselectivities.</div></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"23 18","pages":"Pages 4344-4348"},"PeriodicalIF":2.7000,"publicationDate":"2025-04-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052025002654","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
A kinetic resolution of binols and biphenols has been realized via dehydrogenative coupling with hydrosilanes catalyzed by a frustrated Lewis pair of chiral borane and chiral phosphine. A variety of axially chiral siloxanes, along with the corresponding optically active binols and biphenols, were obtained in good yields with moderate to high enantioselectivities.
期刊介绍：
Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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