V. P. Pashkevych, A. S. Grymalyuk, I. Ye. Kotenko, A. V. Terebilenko, M. M. Kurmach, S. V. Ryabukhin, D. M. Volochnyuk, S. V. Kolotilov
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引用次数: 0
Abstract
It has been shown that the coordination polymer [Pd(2-Pymo)2]n (where 2-Pymo– is anion of 2-hydroxypyrimidine) catalyzes C–C coupling of boronic acids and aryl halides. The process of C–C coupling begins after the induction period, duration of which depends on the structure of a boronic acid and the solvent composition. The catalytic activity of [Pd(2-Pymo)2]n can be associated with the in situ formation of ultra-small palladium nanoparticles formed upon the reduction of Pd2+ by a boronic acid, which results in the destruction of such a complex compound on the surface, whereby the nanoparticles formed move into the colloid solution.
期刊介绍：
Theoretical and Experimental Chemistry is a journal for the rapid publication of research communications and reviews on modern problems of physical chemistry such as:
a) physicochemical bases, principles, and methods for creation of novel processes, compounds, and materials;
b) physicochemical principles of chemical process control, influence of external physical forces on chemical reactions;
c) physical nanochemistry, nanostructures and nanomaterials, functional nanomaterials, size-dependent properties of materials.
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