Lijia Zhou, Xiangjiang Dong, Qiang Li and Xianran Xing
{"title":"Superconductivity in platinum-intercalated 2H-TaS2","authors":"Lijia Zhou, Xiangjiang Dong, Qiang Li and Xianran Xing","doi":"10.1039/D5QI00683J","DOIUrl":null,"url":null,"abstract":"<p >We systematically investigated the superconducting properties of 2<em>H</em>-Pt<small><sub><em>x</em></sub></small>TaS<small><sub>2</sub></small> (0 ≤ <em>x</em> ≤ 0.12). As the platinum (Pt) content increases, the charge density wave (CDW) in 2<em>H</em>-TaS<small><sub>2</sub></small>, which appears at approximately 75 K, is progressively suppressed and completely disappears in 2<em>H</em>-Pt<small><sub>0.06</sub></small>TaS<small><sub>2</sub></small>. Meanwhile, the superconducting transition temperature (<em>T</em><small><sub>c</sub></small>) first increases and then decreases, reaching its maximum value of approximately 4.85 K at <em>x</em> = 0.06. This phenomenon suggests a competitive interplay between CDW and superconductivity (SC) in this system. Further measurements of the superconducting parameters of 2<em>H</em>-Pt<small><sub>0.06</sub></small>TaS<small><sub>2</sub></small> indicate that the enhancement of <em>T</em><small><sub>c</sub></small> is primarily attributed to an increase in the density of states at the Fermi level.</p>","PeriodicalId":79,"journal":{"name":"Inorganic Chemistry Frontiers","volume":" 16","pages":" 4879-4886"},"PeriodicalIF":6.4000,"publicationDate":"2025-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganic Chemistry Frontiers","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2025/qi/d5qi00683j","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
We systematically investigated the superconducting properties of 2H-PtxTaS2 (0 ≤ x ≤ 0.12). As the platinum (Pt) content increases, the charge density wave (CDW) in 2H-TaS2, which appears at approximately 75 K, is progressively suppressed and completely disappears in 2H-Pt0.06TaS2. Meanwhile, the superconducting transition temperature (Tc) first increases and then decreases, reaching its maximum value of approximately 4.85 K at x = 0.06. This phenomenon suggests a competitive interplay between CDW and superconductivity (SC) in this system. Further measurements of the superconducting parameters of 2H-Pt0.06TaS2 indicate that the enhancement of Tc is primarily attributed to an increase in the density of states at the Fermi level.