Optical and Structural Properties of 3R-MoS2 Synthesized at High Pressure

IF 0.7 4区 物理与天体物理 Q4 PHYSICS, MULTIDISCIPLINARY Bulletin of the Lebedev Physics Institute Pub Date : 2025-04-20 DOI:10.3103/S1068335624602814
S. N. Nikolaev, V. S. Krivobok, I. I. Usmanov, E. A. Ekimov, K. M. Kondrina, P. V. Enkovich
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Abstract

The rhombohedral (R3) phase of molybdenum disulfide (MoS2) is synthesized from elemental components at high temperatures and pressures. The crystal structure and lattice constants are determined by full-profile X-ray diffraction analysis of the synthesized powder. Scanning electron microscopy in combination with energy-dispersive X-ray microanalysis confirms the formation of layered crystals with the elemental composition of Mo and S in the ratio of 1 : 2. Luminescence spectra of the 3R-MoS2 bilayer transferred onto a SiO2/Si substrate demonstrate narrow emission lines characteristic of low-defect materials.

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高压合成3R-MoS2的光学和结构性质
在高温高压下合成了二硫化钼(MoS2)的菱面体(R3)相。通过x射线全剖面衍射分析确定了合成粉末的晶体结构和晶格常数。扫描电镜结合能量色散x射线微分析证实了层状晶体的形成,元素组成Mo和S的比例为1:2。转移到SiO2/Si衬底上的3R-MoS2双分子层的发光光谱显示出低缺陷材料的窄发射线特征。
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来源期刊
Bulletin of the Lebedev Physics Institute
Bulletin of the Lebedev Physics Institute PHYSICS, MULTIDISCIPLINARY-
CiteScore
0.70
自引率
25.00%
发文量
41
审稿时长
6-12 weeks
期刊介绍: Bulletin of the Lebedev Physics Institute is an international peer reviewed journal that publishes results of new original experimental and theoretical studies on all topics of physics: theoretical physics; atomic and molecular physics; nuclear physics; optics; lasers; condensed matter; physics of solids; biophysics, and others.
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