The restoration of zinc pollution in smelting site soil using nanohydroxyapatite-modified cyanobacterial biochar and its mechanism

Abstract

Heavy metal pollution in the soils at smelting sites must be effectively controlled. Recent advancements in stabilization technology have shown promising results in the remediation of heavy metal-contaminated soils. In this study, nanohydroxyapatite (nHAP) and cyanobacterial biochar were co-pyrolyzed to produce nHAP-modified cyanobacterial biochar (nHAP-CBC), which was applied to remediate Zn contamination of soils at smelting sites. The remediation effect of nHAP-CBC on Zn-contaminated soil was evaluated using batch experiments, and the materials were characterized using XRD, SEM, TEM, BET, and FTIR. These analyses confirmed the uniform dispersion of nHAP on the CBC to form a stable nHAP-CBC material. The results demonstrated that nHAP-CBC effectively converted Zn from an unstable state to a stable state, achieving a 65.79 % conversion rate and a 64.24 % stabilization rate during toxicity characteristic leaching after 45 days of treatment. nHAP-CBC was the most effective at fixing Zn and significantly increased the organic matter (OM) content, suggesting that OM played a key role in Zn fixation. In conclusion, the nHAP-CBC developed in this study can effectively stabilize heavy metals in smelting site soils and offers promising potential for expanding cyanobacterial resource utilization.