A novel ultra-low relative permittivity Mg2P4O12 metaphosphate ceramic for dielectric resonator antennas

IF 6.2 2区 材料科学 Q1 MATERIALS SCIENCE, CERAMICS Journal of The European Ceramic Society Pub Date : 2025-10-01 Epub Date: 2025-04-23 DOI:10.1016/j.jeurceramsoc.2025.117480
Huanrong Tian , Xu Zhou , Zidong Zhang , Haitao Wu , Yao Liu
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Abstract

Addressing the critical demand for ultra-low relative permittivity ceramics in advanced communication systems, this study developed a novel Mg2P4O12 metaphosphate ceramic. At microwave frequencies, it exhibits excellent performance with εr = 4.61 ± 0.08, Q×f = 51,073 ± 1716 GHz, and τf = −11.46 ± 2.1 ppm/℃, offering significant advantages in low-latency transmission and high temperature stability. Additionally, its low bulk density (∼ 2.50 g/cm3) supports lightweight design of electronic devices. Terahertz time-domain spectroscopy further demonstrated its excellent submillimeter-wave dielectric performance, suggesting potential for achieving higher Q×f values. Consequently, 5 wt% H3BO3 was introduced to improve sintering characteristics, significantly enhancing the quality factor to 61,757 ( ± 1608) GHz. To validate practical application, a broadband DRA was designed using Mg2P4O12+ 5 wt% H3BO3 ceramics, achieving an impressive bandwidth of 27.4 % and high gain of 7.3 dBi, demonstrating great potential for radar communication applications.
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介质谐振器天线用新型超低相对介电常数Mg2P4O12偏磷酸盐陶瓷
针对先进通信系统对超低相对介电常数陶瓷的关键需求,本研究开发了一种新型Mg2P4O12偏磷酸盐陶瓷。在微波频段,它具有优秀的性能与εr = 4.61  ±0.08 ,问51073×f =  ± 1716 GHz,和τf = −11.46 ± 2.1 ppm /℃,提供低延迟传输和高温稳定性具有显著的优势。此外,其低堆积密度(~ 2.50 g/cm3)支持电子设备的轻量化设计。太赫兹时域光谱进一步证明了其优异的亚毫米波介电性能,表明实现更高Q×f值的潜力。因此,加入5 wt% H3BO3可以改善烧结特性,显著提高质量因子至61,757( ± 1608)GHz。为了验证实际应用,采用Mg2P4O12+ 5 wt% H3BO3陶瓷设计了宽带DRA,实现了27.4 %的带宽和7.3 dBi的高增益,显示了雷达通信应用的巨大潜力。
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麦克林
NH4H2PO4
麦克林
MgO
来源期刊
Journal of The European Ceramic Society
Journal of The European Ceramic Society 工程技术-材料科学:硅酸盐
CiteScore
10.70
自引率
12.30%
发文量
863
审稿时长
35 days
期刊介绍: The Journal of the European Ceramic Society publishes the results of original research and reviews relating to ceramic materials. Papers of either an experimental or theoretical character will be welcomed on a fully international basis. The emphasis is on novel generic science concerning the relationships between processing, microstructure and properties of polycrystalline ceramics consolidated at high temperature. Papers may relate to any of the conventional categories of ceramic: structural, functional, traditional or composite. The central objective is to sustain a high standard of research quality by means of appropriate reviewing procedures.
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