Electrochemical tip-enhanced Raman Spectroscopy for microscopic studies of electrochemical interfaces

IF 8.2 1区 化学 Q1 CHEMISTRY, PHYSICAL Surface Science Reports Pub Date : 2022-11-01 DOI:10.1016/j.surfrep.2022.100576
Yasuyuki Yokota , Misun Hong , Norihiko Hayazawa , Yousoo Kim
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引用次数: 4

Abstract

The review describes electrochemical applications of tip-enhanced Raman spectroscopy (TERS). These applications combine the merits of both scanning probe microscopy (SPM) and Raman spectroscopy, which enables us to simultaneously obtain high-resolution images of surface morphology and chemical information under the electrochemical environment. This review, first summarizes the pioneering work done on the TERS systems that operate in liquid and electrochemical environments, and then gives an overview of the typical instrumentation of electrochemical TERS (EC-TERS) based on electrochemical scanning tunneling microscopy (EC-STM). Furthermore, this review summarizes the advancements in EC-TERS studies of events that occur at the interfaces. These include potential dependent structural changes and electrochemical reactions. Finally, we discuss the current issues and future prospects of EC-TERS for microscopic studies of electrochemical interfaces.

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电化学尖端增强拉曼光谱用于电化学界面的微观研究
综述了尖端增强拉曼光谱(TERS)在电化学中的应用。这些应用结合了扫描探针显微镜(SPM)和拉曼光谱的优点,使我们能够同时获得电化学环境下表面形貌和化学信息的高分辨率图像。本文首先综述了在液体和电化学环境下工作的电化学检测系统的开创性工作,然后介绍了基于电化学扫描隧道显微镜(EC-STM)的电化学检测系统的典型仪器。此外,本文还综述了EC-TERS在界面上发生的事件的研究进展。这些包括依赖电位的结构变化和电化学反应。最后,讨论了电化学界面微观研究中存在的问题和未来的发展前景。
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来源期刊
Surface Science Reports
Surface Science Reports 化学-物理:凝聚态物理
CiteScore
15.90
自引率
2.00%
发文量
9
审稿时长
178 days
期刊介绍: Surface Science Reports is a journal that specializes in invited review papers on experimental and theoretical studies in the physics, chemistry, and pioneering applications of surfaces, interfaces, and nanostructures. The topics covered in the journal aim to contribute to a better understanding of the fundamental phenomena that occur on surfaces and interfaces, as well as the application of this knowledge to the development of materials, processes, and devices. In this journal, the term "surfaces" encompasses all interfaces between solids, liquids, polymers, biomaterials, nanostructures, soft matter, gases, and vacuum. Additionally, the journal includes reviews of experimental techniques and methods used to characterize surfaces and surface processes, such as those based on the interactions of photons, electrons, and ions with surfaces.
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