Constituents of Agaricus xanthodermus Genevier: the first naturally endogenous azo compound and toxic phenolic metabolites.

M Gill, R J Strauch
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引用次数: 36

Abstract

Extraction of fresh sporophores of the fungus Agaricus xanthodermus yields 4,4'-dihydroxy-azobenzene, phenol, p-quinol, and 4,4'-dihydroxybiphenyl. This is the first report of an azo compound arising endogenously in nature, while phenol, p-quinol and 4,4'-dihydroxybiphenyl have not previously been isolated from higher fungi. Phenol is present in fruitbodies in sufficiently high concentration to account for the toxicity of A. xanthodermus.

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黄皮蘑菇的成分:第一种天然内源性偶氮化合物和有毒酚类代谢物。
从真菌黄皮蘑菇的新鲜孢子中提取出4,4′-二羟基偶氮苯、苯酚、对喹啉和4,4′-二羟基联苯。这是首次从自然界中分离到偶氮化合物,而苯酚、对喹啉和4,4′-二羟基联苯此前尚未从高等真菌中分离到。酚存在于子实体中,其浓度足够高,足以说明黄皮霉的毒性。
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