Elementary arguments that the Wu–Austin Hamiltonian has no finite ground state (the search for a microscopic foundation of Fröhlichs theory)

H. Bolterauer
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引用次数: 12

Abstract

The Wu–Austin Hamiltonian as the basis for deriving Fröhlichs rate equations from a microscopical point of view has been investigated. In addition to an earlier paper we show in a very easy manner that this or similar Hamiltonians have no lower bound and are therefore unphysical. The perturbation expansion which is the tool to derive Fröhlichs rate equations with this Hamiltonian is not converging. Therefore, the usual derivation of this rate equation is not valid.

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Wu-Austin hamilton量没有有限基态的基本论证(寻找Fröhlichs理论的微观基础)
研究了从微观角度推导Fröhlichs速率方程的Wu-Austin hamilton量。除了之前的一篇论文外,我们用一种很简单的方式证明了这个或类似的哈密顿量没有下界,因此是非物理的。微扰展开是推导Fröhlichs速率方程的工具用这个哈密顿量是不收敛的。因此,通常对这个速率方程的推导是无效的。
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A bibliometric survey and a citation-based bibliography. Bioelectrochemistry and bioenergetics a bibliometric survey of volumes 1–48 Bioelectrochemistry and bioenergetics cited author index Bioelectrochemistry and bioenergetics citation-based bibliography, 1975–1998 Cumulative indexes of volumes 1-49.
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