G Pantazidis, M Scheffler, F D S Simonsen, A Cassidy, P A Jensen, L Hornekær, J D Thrower
{"title":"Deuteration of C<sub>60</sub> on a highly oriented pyrolytic graphite surface.","authors":"G Pantazidis, M Scheffler, F D S Simonsen, A Cassidy, P A Jensen, L Hornekær, J D Thrower","doi":"10.1017/S1743921320000344","DOIUrl":null,"url":null,"abstract":"<p><p>Reactions on carbonaceous surfaces play an important role in processes such as H<sub>2</sub> formation in the interstellar medium. We have investigated the adsorption of C<sub>60</sub> molecules on a highly oriented pyrolytic graphite (HOPG) surface and then exposed them to a beam of deuterium atoms in order to investigate the formation of deuterated fullerenes. Scanning tunneling microscopy (STM) was used to probe the adsorbed molecules and their deuteration. Deuteration of C<sub>60</sub> films results in increased thermal stability of the film, relative to films of pristine C<sub>60</sub>, along with an evolution towards higher deuterated species. The STM data provide confirmatory evidence for the formation of deuterated fullerene species.</p>","PeriodicalId":74548,"journal":{"name":"Proceedings of the International Astronomical Union. International Astronomical Union","volume":"15 Suppl 350","pages":"458-459"},"PeriodicalIF":0.0000,"publicationDate":"2019-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7610475/pdf/EMS120223.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Proceedings of the International Astronomical Union. International Astronomical Union","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1017/S1743921320000344","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2020/10/12 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
Reactions on carbonaceous surfaces play an important role in processes such as H2 formation in the interstellar medium. We have investigated the adsorption of C60 molecules on a highly oriented pyrolytic graphite (HOPG) surface and then exposed them to a beam of deuterium atoms in order to investigate the formation of deuterated fullerenes. Scanning tunneling microscopy (STM) was used to probe the adsorbed molecules and their deuteration. Deuteration of C60 films results in increased thermal stability of the film, relative to films of pristine C60, along with an evolution towards higher deuterated species. The STM data provide confirmatory evidence for the formation of deuterated fullerene species.
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