Basic ammonothermal growth of Gallium Nitride – State of the art, challenges, perspectives

IF 4.5 2区 材料科学 Q1 CRYSTALLOGRAPHY Progress in Crystal Growth and Characterization of Materials Pub Date : 2018-09-01 DOI:10.1016/j.pcrysgrow.2018.05.001
M. Zajac , R. Kucharski , K. Grabianska , A. Gwardys-Bak , A. Puchalski , D. Wasik , E. Litwin-Staszewska , R. Piotrzkowski , J. Z Domagala , M. Bockowski
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引用次数: 71

Abstract

Recent progress in ammonothermal technology of bulk GaN growth in basic environment is presented and discussed in this paper. This method enables growth of two-inch in diameter crystals of outstanding structural properties, with radius of curvature above tens of meters and low threading dislocation density of the order of 5 × 104 cm−2. Crystals with different types of conductivity, n-type with free electron concentration up to 1019 cm−3, p-type with free hole concentration of 1016 cm−3, and semi-insulating with resistivity exceeding 1011 Ω cm, can be obtained. Ammonothermal GaN of various electrical properties is described in terms of point defects present in the material. Potential applications of high-quality GaN substrates are also briefly shown.

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氮化镓的碱性氨热生长-现状,挑战,展望
本文介绍了近年来碱性环境下氮化镓体生长氨热技术的研究进展。这种方法可以生长出两英寸直径的晶体,具有优异的结构性能,曲率半径在几十米以上,螺纹位错密度低,约为5 × 104 cm−2。可以得到不同电导率类型的晶体,自由电子浓度可达1019 cm−3的n型晶体,自由空穴浓度可达1016 cm−3的p型晶体,电阻率超过1011 Ω cm的半绝缘晶体。根据材料中存在的点缺陷描述了各种电性能的氨热氮化镓。本文还简要介绍了高质量氮化镓衬底的潜在应用。
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来源期刊
Progress in Crystal Growth and Characterization of Materials
Progress in Crystal Growth and Characterization of Materials 工程技术-材料科学:表征与测试
CiteScore
8.80
自引率
2.00%
发文量
10
审稿时长
1 day
期刊介绍: Materials especially crystalline materials provide the foundation of our modern technologically driven world. The domination of materials is achieved through detailed scientific research. Advances in the techniques of growing and assessing ever more perfect crystals of a wide range of materials lie at the roots of much of today''s advanced technology. The evolution and development of crystalline materials involves research by dedicated scientists in academia as well as industry involving a broad field of disciplines including biology, chemistry, physics, material sciences and engineering. Crucially important applications in information technology, photonics, energy storage and harvesting, environmental protection, medicine and food production require a deep understanding of and control of crystal growth. This can involve suitable growth methods and material characterization from the bulk down to the nano-scale.
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