Evaluation of the ET-AAS and HG-AAS methods of selenium determination in vegetables

Ondrej Hegedűs , Alžbeta Hegedűsová , Silvia Šimková , Vladimír Pavlík , Klaudia Jomová
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引用次数: 25

Abstract

ET-AAS and HG-AAS methods of selenium determination were compared and evaluated. The ET-AAS method has been followed with deuterium background correction and Zeeman background correction respectively. The following validation parameters were determined: accuracy (under repeatability conditions), trueness, calibration curve and linearity, limit of detection, limit of determination and combined standard uncertainty of the method. The HG-AAS method and the ET-AAS method with Zeeman correction were more suitable for the determination of low selenium concentrations in vegetables. The results were calculated by the standard addition method because of the strong matrix effect.

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et -原子吸收光谱法和hg -原子吸收光谱法测定蔬菜中硒的评价
对ET-AAS法和HG-AAS法测定硒进行了比较评价。对ET-AAS法分别进行了氘背景校正和Zeeman背景校正。确定以下验证参数:准确度(在重复性条件下)、准确度、校准曲线和线性、检测限、测定限和方法的联合标准不确定度。hg -原子吸收光谱法和塞曼校正的et -原子吸收光谱法更适合于蔬菜中低硒含量的测定。由于矩阵效应强,计算结果采用标准加法法。
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