Cage-like metallasilsesquioxanes in catalysis: A review

Mikhail M. Levitsky , Alexey I. Yalymov , Alena N. Kulakova , Аrtem А. Petrov , Аlexey N. Bilyachenko
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引用次数: 56

Abstract

The review describes catalytic properties of a unique class of metal complexes—polycyclic cage-like metallasilsesquioxanes. Article is composed in retrospective manner and reflects the progress of the investigations in the field: from classic applications to recently discovered perspectives of cage-like metallasilsesquioxanes in catalysis of oxidation of С–H compounds.

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笼状金属硅氧烷催化研究进展
综述了一类独特的金属配合物——多环笼状金属硅氧烷的催化性能。文章以回顾的方式组成,反映了该领域的研究进展:从经典应用到最近发现的笼状金属硅氧烷催化С-H化合物氧化的观点。
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期刊介绍: The Journal of Molecular Catalysis A: Chemical publishes original, rigorous, and scholarly full papers that examine the molecular and atomic aspects of catalytic activation and reaction mechanisms in homogeneous catalysis, heterogeneous catalysis (including supported organometallic catalysis), and computational catalysis.
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