Palladium(III) in Synthesis and Catalysis.

Q3 Chemistry Topics in Organometallic Chemistry Pub Date : 2011-01-01 DOI:10.1007/978-3-642-17429-2_6

David C Powers, Tobias Ritter

引用次数: 89

Abstract

While the organometallic chemistry of Pd in its (0), (+II), and (+IV) oxidation states is well-established, organometallic Pd(III) chemistry remains widely unexplored. Few characterized Pd(III) complexes are known, which has inhibited detailed study of the organometallic chemistry of Pd(III). In this review, the potential roles of both mono- and dinuclear Pd(III) complexes in organometallic chemistry will be discussed. While not widely recognized, Pd in the (+III) oxidation state may play a significant role in a variety of known Pd-catalyzed reactions.

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钯(III)的合成与催化。

虽然Pd在(0)，(+II)和(+IV)氧化态的有机金属化学已经建立，但有机金属Pd(III)化学仍然广泛未被探索。已知的Pd(III)配合物很少，这阻碍了Pd(III)有机金属化学的详细研究。本文将讨论单核和双核钯配合物在有机金属化学中的潜在作用。虽然不被广泛认识，但(+III)氧化态的Pd可能在各种已知的Pd催化反应中发挥重要作用。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Topics in Organometallic Chemistry Chemical Engineering-Catalysis

CiteScore

2.70

自引率

0.00%

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期刊介绍： The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience.

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