Interaction of the O-Benzoyl-β-aminopropioamidoximes with Lawesson's Reagent and Spectral Characterization of the Products.

ISRN Organic Chemistry Pub Date : 2012-03-22 eCollection Date: 2012-01-01 DOI:10.5402/2012/945893
Lyudmila Kayukova, Kaldubai Praliyev, Ulan Kemelbekov, Asel Abdildanova, Vanda Gutyar
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Abstract

Interaction of O-benzoyl-β-aminopropioamidoximes [β-amino group: pyperidin-1-yl; morpholin-1-yl; thiomorpholin-1-yl; 4-phenylpiperazin-1-yl; benzimidazol-1-yl] with Lawesson's reagent was done in tetrahydrofuran at heating to 70°C during 10 h. New O-thiobenzoyl-β-aminopropioamidoximes were obtained with the outputs 57-96%; they were characterized with the help of physicochemical, IR, and NMR spectra.

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邻苯甲酰-β-氨基丙胺肟与Lawesson试剂的相互作用及产物的光谱表征。
邻苯甲酰-β-氨基丙酰胺肟的相互作用[β-氨基:吡啶-1-基]morpholin-1-yl;thiomorpholin-1-yl;4-phenylpiperazin-1-yl;用Lawesson试剂在四氢呋喃中加热至70℃,反应10 h。得到新的o -硫代苯甲酰-β-氨基丙胺肟,收率为57 ~ 96%;通过物理化学、红外和核磁共振光谱对其进行了表征。
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