{"title":"Poly[diaqua[μ4-4-(isonicotinamido)phthalato]nickel(II)] displaying an sra topology.","authors":"Man-Sheng Chen, Jin-Sheng Xu, Yi-Fang Deng, Chun-Hua Zhang","doi":"10.1107/S0108270113023846","DOIUrl":null,"url":null,"abstract":"<p><p>In the title compound, [Ni(C14H8N2O5)(H2O)2]n, the Ni(II) cation is six-coordinate with a slightly distorted octahedral coordination geometry and the 4-(isonicotinamido)phthalate ligand links the Ni(II) centres into a three-dimensional structure with sra topology. The structure is also stabilized by N-H···O hydrogen bonding between the uncoordinated amide groups of the ligand and extensive O-H···O hydrogen bonding between the two coordinated water molecules. The magnetic and thermal stability properties of the title compound are also discussed.</p>","PeriodicalId":7368,"journal":{"name":"Acta crystallographica. Section C, Crystal structure communications","volume":"69 Pt 10","pages":"1124-7"},"PeriodicalIF":0.8000,"publicationDate":"2013-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1107/S0108270113023846","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Acta crystallographica. Section C, Crystal structure communications","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1107/S0108270113023846","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2013/9/6 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
In the title compound, [Ni(C14H8N2O5)(H2O)2]n, the Ni(II) cation is six-coordinate with a slightly distorted octahedral coordination geometry and the 4-(isonicotinamido)phthalate ligand links the Ni(II) centres into a three-dimensional structure with sra topology. The structure is also stabilized by N-H···O hydrogen bonding between the uncoordinated amide groups of the ligand and extensive O-H···O hydrogen bonding between the two coordinated water molecules. The magnetic and thermal stability properties of the title compound are also discussed.
期刊介绍：
Acta Crystallographica Section C: Structural Chemistry is continuing its transition to a journal that publishes exciting science with structural content, in particular, important results relating to the chemical sciences. Section C is the journal of choice for the rapid publication of articles that highlight interesting research facilitated by the determination, calculation or analysis of structures of any type, other than macromolecular structures. Articles that emphasize the science and the outcomes that were enabled by the study are particularly welcomed. Authors are encouraged to include mainstream science in their papers, thereby producing manuscripts that are substantial scientific well-rounded contributions that appeal to a broad community of readers and increase the profile of the authors.
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