Crystal structure of trans-aqua-(perchlorato-κO)bis-(propane-1,3-di-amine-κ(2) N,N')copper(II) perchlorate.

IF 0.9 Acta crystallographica. Section E, Structure reports online Pub Date : 2014-10-31 eCollection Date: 2014-11-01 DOI:10.1107/S1600536814023496
J Govindaraj, K Rajkumar, A S Ganeshraja, K Anbalagan, A SubbiahPandi
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引用次数: 1

Abstract

In the title compound, [Cu(ClO4)(C3H10N2)2(H2O)]ClO4, the Cu(II) atom has a distorted octa-hedral coordination sphere and is coordinated by the N atoms of two propane-1,3-di-amine ligands in the equatorial plane. The axial positions are occupied by a water O atom and an O atom of a disordered perchlorate anion [occupancy ratio 0.631 (9):0.369 (9)]. In the crystal, the various components are linked via O-H⋯O, N-H⋯O and C-H⋯O hydrogen bonds, forming sheets lying parallel to (001).

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高氯酸反式水-(高氯酸-κ o)双-(丙烷-1,3-二胺-κ(2) N,N')铜(II)的晶体结构
在标题化合物[Cu(ClO4)(C3H10N2)2(H2O)]ClO4中,Cu(II)原子具有畸变的八面体配位球,并在赤道面上由两个丙烷-1,3-二胺配体的N原子配位。轴向位置由一个水O原子和一个无序高氯酸盐阴离子的O原子占据[占据比为0.631(9):0.369(9)]。在晶体中,各种成分通过O- h⋯O, N-H⋯O和C-H⋯O氢键连接,形成平行于(001)的薄片。
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审稿时长
1.3 months
期刊介绍: Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.
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