Definitive crystal structure of 1,1'-bis-[1,2-dicarba-closo-dodeca-borane(11)].

IF 0.9 Acta crystallographica. Section E, Structure reports online Pub Date : 2014-11-05 eCollection Date: 2014-12-01 DOI:10.1107/S1600536814023897

Wing Y Man, Georgina M Rosair, Alan J Welch

引用次数: 8

Abstract

In the title compound, C4H22B20, the two {1,2-closo-C2B10H11} cages are linked across a centre of inversion with a C-C distance of 1.5339 (11) Å. By careful analysis of the structure, it is established that the non-linking cage C atom is equally disordered over cage vertices 2 and 3.

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1,1'-双-[1,2-二碳-近十二硼烷[11]的确定晶体结构。

在标题化合物C4H22B20中，两个{1,2- close - c2b10h11}笼穿过反转中心连接，C-C距离为1.5339 (11)Å。通过对结构的仔细分析，确定了非连接笼C原子在笼顶点2和3上具有同样的无序性。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Acta crystallographica. Section E, Structure reports online 化学-晶体学

自引率

33.30%

发文量

审稿时长

1.3 months

期刊介绍： Acta Crystallographica Section E: Structure Reports Online is the IUCr highly popular open-access structural journal. It provides a simple and easily accessible publication mechanism for the growing number of inorganic, metal-organic and organic crystal structure determinations. The electronic submission, validation, refereeing and publication facilities of the journal ensure very rapid and high-quality publication, whilst key indicators and validation reports provide measures of structural reliability. In 2009, the journal published over 4000 structures. The average publication time is less than one month.