Transition Metals Catalyzed Element-Cyano Bonds Activations.

IF 9.3 2区 化学 Q1 CHEMISTRY, PHYSICAL Catalysis Reviews-Science and Engineering Pub Date : 2014-07-01 DOI:10.1080/01614940.2014.920178
Rui Wang, John R Falck
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引用次数: 15

Abstract

Cyano group as a versatile functionalized intermediate has been explored for several decades, as it readily transfers to many useful functionalization groups such as amine, amide, acid, etc., which make it possess high popularization and use value in organic synthesis. Reactions involved with element-cyano bond cleavage can provide not only a new cyano group but also a freshly functionalized skeleton in one-pot, consequently making it of high importance. The highlights reviewed herein include H-CN, Si-CN, C-CN, B-CN, Sn-CN, Ge-CN, S-CN, Halo-CN, N-CN, and O-CN bonds cleavages and will summarize progress in such an important research area. This review article will focus on transition metal catalyzed reactions involving element-cyano bond activation.

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过渡金属催化元素-氰基键活化。
氰基作为一种多功能功能化中间体已经被探索了几十年,因为它很容易转移到许多有用的功能化基团,如胺、酰胺、酸等,这使得它在有机合成中具有很高的推广和使用价值。元素-氰基键裂解反应不仅可以生成新的氰基,还可以在一个锅中生成新的官能化骨架,因此具有重要的意义。本文综述了H-CN、Si-CN、C-CN、B-CN、Sn-CN、Ge-CN、S-CN、Halo-CN、N-CN和O-CN键的裂解,并将总结这一重要研究领域的进展。本文将重点介绍过渡金属催化的元素-氰基键活化反应。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
22.30
自引率
2.80%
发文量
29
期刊介绍: Catalysis Reviews is dedicated to fostering interdisciplinary perspectives in catalytic science and engineering, catering to a global audience of industrial and academic researchers. This journal serves as a bridge between the realms of heterogeneous, homogeneous, and bio-catalysis, providing a crucial and critical evaluation of the current state of catalytic science and engineering. Published topics encompass advances in technology and theory, engineering and chemical aspects of catalytic reactions, reactor design, computer models, analytical tools, and statistical evaluations.
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