Maksym Dekhtiarenko , György Szalóki , Vincent Croué , Jennifer Bou Zeid , David Canevet , Magali Allain , Vincent Carré , Frédéric Aubriet , Zoia Voitenko , Marc Sallé , Sébastien Goeb
{"title":"Playing with the cavity size of exTTF-based self-assembled cages†","authors":"Maksym Dekhtiarenko , György Szalóki , Vincent Croué , Jennifer Bou Zeid , David Canevet , Magali Allain , Vincent Carré , Frédéric Aubriet , Zoia Voitenko , Marc Sallé , Sébastien Goeb","doi":"10.1039/d3qo00214d","DOIUrl":null,"url":null,"abstract":"<div><p>M<sub>4</sub>L<sub>2</sub> metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.</p></div>","PeriodicalId":94379,"journal":{"name":"Organic chemistry frontiers : an international journal of organic chemistry","volume":"10 7","pages":"Pages 1803-1810"},"PeriodicalIF":0.0000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic chemistry frontiers : an international journal of organic chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S2052411023006004","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
M4L2 metalla-cages bearing large electron-rich ovoid cavities constructed through coordination-driven self-assembly from square planar palladium complexes and extended tetrathiafulvalene (exTTF)-based ligands are depicted. Their binding properties for polyaromatic hydrocarbons (PAHs) or zinc tetraphenylporphyrin have been evaluated and compared with previously described smaller cage analogues, showing a high size selectivity.