{"title":"Visible-light-induced defluorinative carbonylative coupling of alkyl iodides with α-trifluoromethyl substituted styrenes†","authors":"Bo Chen , Kai Yu , Xiao-Feng Wu","doi":"10.1039/d2ob00916a","DOIUrl":null,"url":null,"abstract":"<div><p>A visible-light-mediated defluorinative carbonylative cross-coupling of alkyl iodides with α-trifluoromethyl styrenes has been developed. The reaction occurs at room temperature under blue light irradiation, and various <em>gem</em>-difluoroalkenes were obtained in moderate to good yields. Synthetic transformations of the obtained product were performed as well.</p></div>","PeriodicalId":96,"journal":{"name":"Organic & Biomolecular Chemistry","volume":"20 26","pages":"Pages 5264-5269"},"PeriodicalIF":2.7000,"publicationDate":"2022-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Organic & Biomolecular Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1477052022097191","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, ORGANIC","Score":null,"Total":0}
引用次数: 0
Abstract
A visible-light-mediated defluorinative carbonylative cross-coupling of alkyl iodides with α-trifluoromethyl styrenes has been developed. The reaction occurs at room temperature under blue light irradiation, and various gem-difluoroalkenes were obtained in moderate to good yields. Synthetic transformations of the obtained product were performed as well.
期刊介绍：
Organic & Biomolecular Chemistry is an international journal using integrated research in chemistry-organic chemistry. Founded in 2003 by the Royal Society of Chemistry, the journal is published in Semimonthly issues and has been indexed by SCIE, a leading international database. The journal focuses on the key research and cutting-edge progress in the field of chemistry-organic chemistry, publishes and reports the research results in this field in a timely manner, and is committed to becoming a window and platform for rapid academic exchanges among peers in this field. The journal's impact factor in 2023 is 2.9, and its CiteScore is 5.5.
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